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- W388750185 abstract "The title compound, [Rh2Ru(CN)2Cl2(C8H12)2(C5H9N)4], was obtained from the reaction of the chloro(1,5-cyclooctadiene)rhodium(I) dimer with trans-dicyanotetra(tert-butyl isocyanide)ruthenium(II) by cleavage of the chloro bridges in the dimeric rhodium starting complex. The molecular structure shows the Ru atom in a nearly ideal octahedral coordination geometry, whereas the Rh atoms are situated in square-planar ligand environments. The central ruthenium ion is located on a crystallographic twofold axis. The crystal structure is realized by infinite chains of the trinuclear complex units which are connected by C—H⋯Cl interactions. These chains are further linked by another C—H⋯Cl interaction to produce the observed three-dimensional structure." @default.
- W388750185 created "2016-06-24" @default.
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- W388750185 date "2005-09-28" @default.
- W388750185 modified "2023-10-16" @default.
- W388750185 title "Tetrakis(<i>tert</i>-butyl isocyanide-2κ<i>C</i>)dichloro-1κ<i>Cl</i>,3κ<i>Cl</i>-di-μ-cyano-1κ<i>N</i>:2κ<i>C</i>;2κ<i>C</i>:3κ<i>N</i>-bis[1,3(η<sup>4</sup>)-cycloocta-1,5-diene]dirhodium(I)ruthenium(II)" @default.
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- W388750185 doi "https://doi.org/10.1107/s1600536805030461" @default.
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