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- W40242004 abstract "Rotaxanes and porphyrins are two particularly active fields of research in chemistry. However,molecules that combine the interesting properties of these types of structures are not so common. In this thesis we describe new porphyrin-based multi-rotaxanes, whose syntheses constitute interesting challenges.Porphyrins linked to two or four coordinating macrocycles were synthesised. The gathering-andthreading effect of copper(I) was used to thread molecular rods through the rings; the subsequent introduction of stoppers led to the formation of rotaxanes. In the case of the porphyrinic bis-macrocycle a [4]rotaxane was obtained. Host/guest complexation studies with rigid nitrogen ligands showed that the rotaxane behaves as a distensible molecular receptor that can adopt an inflated or deflated conformation and adjust its shape to the size of the guest. In the case of the porphyrinic tetra-macrocycle the formation of a [3]rotaxane of novel architecture was observed.The synthesis of a new, more rigid bis-macrocycle is in progress. This compound will be used for the construction of a [4]rotaxane that could act as a molecular press able to change the conformation of a guest substrate by compression." @default.
- W40242004 created "2016-06-24" @default.
- W40242004 creator A5081948328 @default.
- W40242004 date "2012-04-20" @default.
- W40242004 modified "2023-09-27" @default.
- W40242004 title "Porphyrin-based [3]- and [4]rotaxanes : towards an adaptable molecular receptor" @default.
- W40242004 hasPublicationYear "2012" @default.
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