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- W405928557 abstract "Bis(1,3,5-triazapentadienate)zinc complexes [N(Ph)C(R)NC(R)N(SiMe3)]2Zn (R = NMe2, 1; 1-piperidino, 2) and (1,3,5-triazapentadienate)aluminum dichloride [N(Ph)C(NMe2)NC(NMe2)N(SiMe3)]AlCl2·C9H18N6 (3) were synthesized and structurally characterized by X-ray crystallography and spectroscopic techniques. The X-ray structures of 1–3 showed that they crystallize in the triclinic system and prefer coordination to the zinc and aluminum centers via the terminal N atoms of the NCNCN ligand backbone, affording tetrahedral geometry. The catalytic properties of 1 and 2 were evaluated." @default.
- W405928557 created "2016-06-24" @default.
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- W405928557 date "2015-08-01" @default.
- W405928557 modified "2023-10-14" @default.
- W405928557 title "Zinc and aluminum complexes derived from 2, 4-N, N′-disubstituted 1, 3, 5-triazapentadienyl ligands: Synthesis, characterization and catalysis of the ring-opening polymerization of rac-lactide" @default.
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- W405928557 doi "https://doi.org/10.1016/j.inoche.2015.05.021" @default.
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