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• W40746870 abstract "The coadsorption of H2O and NO2 molecules on a well-ordered, ultrathin θ-Al2O3/NiAl(100) film surface was studied using temperature programmed desorption (TPD), infrared reflection absorption spectroscopy (IRAS), and X-ray photoelectron spectroscopy (XPS). For H2O and NO2 monolayers adsorbed separately on the θ-Al2O3/NiAl(100) surface, adsorption energies were estimated to be 44.8 and 36.6 kJ/mol, respectively. Coadsorption systems prepared by sequential deposition of NO2 and H2O revealed the existence of coverage and temperature-dependent adsorption regimes where H2O molecules and the surface NOx species (NO2/N2O4/NO2-,NO3-) form segregated and/or mixed domains. Influence of the changes in the crystallinity of solid water (amorphous vs crystalline) on the coadsorption properties of the NO2/H2O/θ-Al2O3/NiAl(100) system is also discussed." @default.
• W40746870 created "2016-06-24" @default.
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• W40746870 date "2006-03-31" @default.
• W40746870 modified "2023-09-29" @default.
• W40746870 title "Low Temperature H₂O and NO₂ Coadsorption on θ-Al₂O₃/NiAl(100) Ultrathin Films" @default.
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• W40746870 doi "https://doi.org/10.1021/jp057534c" @default.
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