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• W41142755 abstract "The adsorption of sulfur hexafluoride (SF 6 ) in a foam-like graphite material (GRAFOAM) has been studied in a temperature range from 0°C to 60°C, ie, temperatures from 45 K below to 15 K above the critical temperature (T c = 45.5°C). At subcritical temperatures (T < T c ) the isotherms were measured up to nearly the saturation pressure. At supercritical temperatures (T > T c ) the measurements extended up to 100 bar, ie more than twice the critical pressure (p = 37.6 bar). The results are expressed by the surface excess amount of the adsorbed fluid. The resulting surface excess isotherms are similar to isotherms on nonporous graphite substrates. However, a pronounced adsorption hysteresis was found at both subcritical and supercritical temperatures. It is argued that this hysteresis effect is due to a pressure-induced partial exfoliation of aggregates of graphite flakes, which is partly reversible when the stress is released." @default.
• W41142755 created "2016-06-24" @default.
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• W41142755 date "1988-01-01" @default.
• W41142755 modified "2023-09-27" @default.
• W41142755 title "Hysteresis Effects in the High-Pressure Adsorption of Gases in Graphite Foam (GRAFOAM)" @default.
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• W41142755 doi "https://doi.org/10.1016/s0167-2991(09)60744-8" @default.
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