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- W413462528 abstract "Introduction Among a wide variety of photosensitive compounds 2 dendrimers with photoactive groups allocated in different parts of their superbranched molecules are of particular interest. In spite of a large number of publications devoted to investigation of photophysical and photochemical properties of dendrimer solutions, any influence of a generation number of such compounds on a kinetics of isomerization process was not revealed by now. In this work we synthesized a number of carbosilane dendrimers of 1, 3 and 5 generations (Gn) with 8, 32, and 128 terminal ethoxyazobenzene (AzoEt) groups in order to evaluate an influence of the dendritic matrix size (generation number) on the photochemical properties of such complex molecules. General structural formulae of the dendrimers studied is shown in Figure 1." @default.
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- W413462528 date "2002-01-01" @default.
- W413462528 modified "2023-09-23" @default.
- W413462528 title "Strong influence of generation number on the kinetics of Z/E isomerization in carbosilane dendrimers with azobenzene terminal groups" @default.
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