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- W4200016580 abstract "A library of fluorinated aryl diazomethanes were polymerized using BF3·OEt2 as a catalyst. The polymerization of 2,3,4,5,6-pentafluorophenyl diazomethane was found to be controlled, permitted chain extensions, and facilitated access to a series of block copolymers. Moreover, the polymer chains grew in one carbon increments (so-called C1 polymerizations) and, as such, afforded highly substituted polymers that featured aryl units pendant to every carbon atom of the backbone. The polymers were characterized using size exclusion chromatography, various spectroscopic techniques, and a series of static and dynamic contact angle measurements. Compared to less-substituted analogues that were prepared using typical C2 polymerization methodologies, the C1 fluorinated polymers were found to be more hydrophobic while maintaining a sufficient solubility to be processed into robust films." @default.
- W4200016580 created "2021-12-31" @default.
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- W4200016580 date "2021-12-13" @default.
- W4200016580 modified "2023-09-30" @default.
- W4200016580 title "C1 Polymerization of Fluorinated Aryl Diazomethanes" @default.
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- W4200016580 doi "https://doi.org/10.1021/acsmacrolett.1c00686" @default.
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