Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200061442> ?p ?o ?g. }
- W4200061442 endingPage "321" @default.
- W4200061442 startingPage "321" @default.
- W4200061442 abstract "In this study, nanocomposites based on polycaprolactone (PCL) and two types of mesoporous silicas, MCM-41 and SBA-15, were attained by melt extrusion. The effect of the silica incorporated within the PCL matrix was observed, firstly, in the morphological characteristics and degradation behavior of the resultant composites. DSC experiments provided information on the existence of confinement in the PCL–SBA-15 materials through the appearance of an additional small endotherm, located at about 25–50 °C, and attributed to the melting of constrained crystallites. Displacement to a slightly lower temperature of this endothermic event was observed in the first heating run of PCL–MCM-41 composites, attributed to the inferior pore size in the MCM-41 particles. Thus, this indicates variations in the inclusion of PCL chains within these two mesostructures with different pore sizes. Real-time variable-temperature small-angle X-ray scattering (SAXS) experiments with synchrotron radiation were crucial to confirm the presence of PCL within MCM-41 and SBA-15 pores. Accurate information was also deduced from these measurements regarding the influence of these two mesoporous MCM-41 and SBA-15 silicas on PCL long spacing. The differences found in these morphological and structural features were responsible for the ultimate mechanical response exhibited by the two sets of PCL nanocomposites, with a considerably higher increase of mechanical parameters in the SBA-15 family." @default.
- W4200061442 created "2021-12-31" @default.
- W4200061442 creator A5031789908 @default.
- W4200061442 creator A5040839495 @default.
- W4200061442 creator A5042824645 @default.
- W4200061442 creator A5066794822 @default.
- W4200061442 creator A5069031826 @default.
- W4200061442 creator A5070673060 @default.
- W4200061442 date "2021-12-10" @default.
- W4200061442 modified "2023-10-11" @default.
- W4200061442 title "Confinement in Extruded Nanocomposites Based on PCL and Mesoporous Silicas: Effect of Pore Sizes and Their Influence in Ultimate Mechanical Response" @default.
- W4200061442 cites W1581285898 @default.
- W4200061442 cites W1911434658 @default.
- W4200061442 cites W1966200634 @default.
- W4200061442 cites W1979885894 @default.
- W4200061442 cites W1982615665 @default.
- W4200061442 cites W1982784029 @default.
- W4200061442 cites W1984475138 @default.
- W4200061442 cites W1988745485 @default.
- W4200061442 cites W1994609967 @default.
- W4200061442 cites W1995041236 @default.
- W4200061442 cites W1998109680 @default.
- W4200061442 cites W2018451338 @default.
- W4200061442 cites W2022351794 @default.
- W4200061442 cites W2026155132 @default.
- W4200061442 cites W2035296584 @default.
- W4200061442 cites W2039458290 @default.
- W4200061442 cites W2041566541 @default.
- W4200061442 cites W2045300819 @default.
- W4200061442 cites W2051603731 @default.
- W4200061442 cites W2052913314 @default.
- W4200061442 cites W2053334003 @default.
- W4200061442 cites W2058261287 @default.
- W4200061442 cites W2058473812 @default.
- W4200061442 cites W2064527426 @default.
- W4200061442 cites W2077745611 @default.
- W4200061442 cites W2089429206 @default.
- W4200061442 cites W2101276326 @default.
- W4200061442 cites W2109452850 @default.
- W4200061442 cites W2138643896 @default.
- W4200061442 cites W2164600066 @default.
- W4200061442 cites W2199144780 @default.
- W4200061442 cites W2209201076 @default.
- W4200061442 cites W2315880435 @default.
- W4200061442 cites W2411921434 @default.
- W4200061442 cites W2413004169 @default.
- W4200061442 cites W2532266072 @default.
- W4200061442 cites W2592636257 @default.
- W4200061442 cites W2808723657 @default.
- W4200061442 cites W2810669174 @default.
- W4200061442 cites W2883779028 @default.
- W4200061442 cites W2896518416 @default.
- W4200061442 cites W2989333106 @default.
- W4200061442 cites W2993531794 @default.
- W4200061442 cites W2998371256 @default.
- W4200061442 cites W39236032 @default.
- W4200061442 doi "https://doi.org/10.3390/jcs5120321" @default.
- W4200061442 hasPublicationYear "2021" @default.
- W4200061442 type Work @default.
- W4200061442 citedByCount "5" @default.
- W4200061442 countsByYear W42000614422022 @default.
- W4200061442 countsByYear W42000614422023 @default.
- W4200061442 crossrefType "journal-article" @default.
- W4200061442 hasAuthorship W4200061442A5031789908 @default.
- W4200061442 hasAuthorship W4200061442A5040839495 @default.
- W4200061442 hasAuthorship W4200061442A5042824645 @default.
- W4200061442 hasAuthorship W4200061442A5066794822 @default.
- W4200061442 hasAuthorship W4200061442A5069031826 @default.
- W4200061442 hasAuthorship W4200061442A5070673060 @default.
- W4200061442 hasBestOaLocation W42000614421 @default.
- W4200061442 hasConcept C119292831 @default.
- W4200061442 hasConcept C120665830 @default.
- W4200061442 hasConcept C121332964 @default.
- W4200061442 hasConcept C127413603 @default.
- W4200061442 hasConcept C131888329 @default.
- W4200061442 hasConcept C137637335 @default.
- W4200061442 hasConcept C150394285 @default.
- W4200061442 hasConcept C159985019 @default.
- W4200061442 hasConcept C161790260 @default.
- W4200061442 hasConcept C178790620 @default.
- W4200061442 hasConcept C185592680 @default.
- W4200061442 hasConcept C191486275 @default.
- W4200061442 hasConcept C191897082 @default.
- W4200061442 hasConcept C192562407 @default.
- W4200061442 hasConcept C20976626 @default.
- W4200061442 hasConcept C2778958987 @default.
- W4200061442 hasConcept C2779868350 @default.
- W4200061442 hasConcept C39519442 @default.
- W4200061442 hasConcept C42360764 @default.
- W4200061442 hasConcept C521977710 @default.
- W4200061442 hasConcept C55493867 @default.
- W4200061442 hasConcept C82776694 @default.
- W4200061442 hasConcept C92880739 @default.
- W4200061442 hasConcept C97355855 @default.
- W4200061442 hasConceptScore W4200061442C119292831 @default.
- W4200061442 hasConceptScore W4200061442C120665830 @default.
- W4200061442 hasConceptScore W4200061442C121332964 @default.
- W4200061442 hasConceptScore W4200061442C127413603 @default.