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- W4200123810 abstract "Abstract Trade-off between permeability and nanometer-level selectivity is an inherent shortcoming of membrane-based separation of molecules, while most highly porous materials with high adsorption capacity lack solution processability and stability for achieving adsorption-based molecule separation. We hereby report a hydrophilic amidoxime modified polymer of intrinsic microporosity (AOPIM-1) as a membrane adsorption material to selectively adsorb and separate small organic molecules from water with ultrahigh processing capacity. The membrane adsorption capacity for Rhodamine B reaches 26.114 g m −2 , 10~1000 times higher than previously reported adsorptive membranes. Meanwhile, the membrane achieves >99.9% removal of various nano-sized organic molecules with water flux 2 orders of magnitude higher than typical pressure-driven membranes of similar rejections. This work confirms the feasibility of microporous polymers for membrane adsorption with unprecedented capacity, and provides the possibility of adsorptive membranes for molecular separation." @default.
- W4200123810 created "2021-12-31" @default.
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- W4200123810 date "2021-12-10" @default.
- W4200123810 modified "2023-09-23" @default.
- W4200123810 title "Microporous Polymer Adsorptive Membranes with Unprecedented Processing Capacity for Molecular Separation" @default.
- W4200123810 doi "https://doi.org/10.21203/rs.3.rs-1132837/v1" @default.
- W4200123810 hasPublicationYear "2021" @default.
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