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- W4200126552 abstract "Abstract Herein, we report the efficient degradation of N 2 O with a well‐defined bis(silylene)amido iron complex as catalyst. The deoxygenation of N 2 O using the iron silanone complex 4 as a catalyst and pinacolborane (HBpin) as a sacrificial reagent proceeds smoothly at 50 °C to form N 2 , H 2 , and (pinB) 2 O. Mechanistic studies suggest that the iron–silicon cooperativity is the key to this catalytic transformation, which involves N 2 O activation, H atom transfer, H 2 release and oxygenation of the boron sites. This approach has been further developed to enable catalytic reductions of nitro compounds, producing amino‐boranes with good functional‐group tolerance and excellent chemoselectivity." @default.
- W4200126552 created "2021-12-31" @default.
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- W4200126552 date "2021-12-01" @default.
- W4200126552 modified "2023-10-14" @default.
- W4200126552 title "Deoxygenation of Nitrous Oxide and Nitro Compounds Using Bis(N‐Heterocyclic Silylene)Amido Iron Complexes as Catalysts" @default.
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- W4200126552 doi "https://doi.org/10.1002/ange.202114598" @default.
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