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- W4200132893 abstract "Abstract While of interest, synthetically feasible access to boryl ligands and complexes remains limited, meaning such complexes remain underexploited in catalysis. For bidentate boryl ligands, oxidative addition of boranes to low‐valent Ir I or Pt 0 are the only examples yet reported. As part of our interest in developing improved group 10 ethylene polymerization catalysts, we present here an optimized synthesis of a novel, rigid borane/phosphine ligand and its Ni 0 σ‐borane complex. From the latter, an unprecedented oxidative dehydrochloroborylation, to give a Ni II boryl complex, was achieved. Furthermore, this new B/P ligand allowed the nickel‐catalyzed polymerization of ethylene, which suggests that Ni 0 σ‐hydroborane complexes act as masked Ni II boryl hydride reagents." @default.
- W4200132893 created "2021-12-31" @default.
- W4200132893 creator A5037298718 @default.
- W4200132893 creator A5039294749 @default.
- W4200132893 date "2021-12-14" @default.
- W4200132893 modified "2023-10-01" @default.
- W4200132893 title "A Ni<sup>0</sup> σ‐Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization" @default.
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- W4200132893 doi "https://doi.org/10.1002/ange.202111691" @default.
- W4200132893 hasPublicationYear "2021" @default.
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