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- W4200134429 abstract "Chemoselective disulfide formation is accomplished through a thiol-disulfide interchange approach using sec-isoamyl mercaptan (SIT) as an alkyl sulfenyl-protecting group of one of the Cys residues involved in the pairing. SIT has a dual and unique characteristic, acting as a masking group during the synthesis and directing disulfide formation in the presence of a free thiol. This novel approach is illustrated by the synthesis of several peptides of biological interest." @default.
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- W4200134429 date "2021-12-15" @default.
- W4200134429 modified "2023-10-02" @default.
- W4200134429 title "Chemoselective Disulfide Formation by Thiol-Disulfide Interchange in SIT-Protected Cysteinyl Peptides" @default.
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- W4200134429 doi "https://doi.org/10.1021/acs.joc.1c02705" @default.
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