Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200170448> ?p ?o ?g. }
- W4200170448 endingPage "134178" @default.
- W4200170448 startingPage "134178" @default.
- W4200170448 abstract "The development of catalysts for the resource utilization of potent greenhouse gases, hydrofluorocarbons (HFCs) by catalytic pyrolysis is of great significance to alleviate the greenhouse effect. Fabricating small catalyst particles with high specific surface area leading to more Lewis acid sites is the effective strategies to achieve highly functional catalysts. However, catalysts tend to sinter at elevated temperatures. Herein, we synthesized carbon matrix confined Al2O3 clusters via the calcination of MIL-53-Al under N2 atmosphere. Then the Al2O3 clusters were in situ fluorinated and turned into AlF3 clusters accordingly. The derived carbon confined AlF3 clusters exhibited outstanding sintering resistance even following thermal treatment at 600 °C. Moreover, the carbon confined AlF3 clusters presented superior catalytic performance for 1,1-difluoroethane (HFC-152a) conversion with near 40% higher than that of AlF3 prepared by traditional precipitation. The excellent catalytic activity and stability were mainly ascribed to the abundant under-coordinated Al species with strong interaction with carbon matrix and high specific surface area. Thus, in this paper, we developed new practicable method to synthesize highly efficient Lewis acid catalysts with strong sintering resistance and abundant acid sites." @default.
- W4200170448 created "2021-12-31" @default.
- W4200170448 creator A5005141691 @default.
- W4200170448 creator A5014528965 @default.
- W4200170448 creator A5016881517 @default.
- W4200170448 creator A5021906210 @default.
- W4200170448 creator A5032441946 @default.
- W4200170448 creator A5042103020 @default.
- W4200170448 creator A5071437727 @default.
- W4200170448 creator A5078040970 @default.
- W4200170448 date "2022-03-01" @default.
- W4200170448 modified "2023-10-16" @default.
- W4200170448 title "Under-coordinated AlF3 clusters confined in carbon matrix with robust sintering resistance for dehydrofluorination of hydrofluorocarbons" @default.
- W4200170448 cites W1781570046 @default.
- W4200170448 cites W1823521176 @default.
- W4200170448 cites W1966892664 @default.
- W4200170448 cites W1978125921 @default.
- W4200170448 cites W1989683516 @default.
- W4200170448 cites W2008301000 @default.
- W4200170448 cites W2024100314 @default.
- W4200170448 cites W2034914607 @default.
- W4200170448 cites W2039151640 @default.
- W4200170448 cites W2050809698 @default.
- W4200170448 cites W2054938727 @default.
- W4200170448 cites W2055528381 @default.
- W4200170448 cites W2058292283 @default.
- W4200170448 cites W2060654243 @default.
- W4200170448 cites W2074588470 @default.
- W4200170448 cites W2075937779 @default.
- W4200170448 cites W2085264552 @default.
- W4200170448 cites W2103313166 @default.
- W4200170448 cites W2157344324 @default.
- W4200170448 cites W2473924893 @default.
- W4200170448 cites W2562135396 @default.
- W4200170448 cites W2562629497 @default.
- W4200170448 cites W2610608721 @default.
- W4200170448 cites W2625838247 @default.
- W4200170448 cites W2766907171 @default.
- W4200170448 cites W2799850516 @default.
- W4200170448 cites W2807734377 @default.
- W4200170448 cites W2832432899 @default.
- W4200170448 cites W2888219264 @default.
- W4200170448 cites W2891921021 @default.
- W4200170448 cites W2904333852 @default.
- W4200170448 cites W2920793393 @default.
- W4200170448 cites W2957869873 @default.
- W4200170448 cites W2959643213 @default.
- W4200170448 cites W2971476249 @default.
- W4200170448 cites W2972799534 @default.
- W4200170448 cites W2973123184 @default.
- W4200170448 cites W2977837898 @default.
- W4200170448 cites W2980758800 @default.
- W4200170448 cites W2981998282 @default.
- W4200170448 cites W3002235605 @default.
- W4200170448 cites W3014491085 @default.
- W4200170448 cites W3023707868 @default.
- W4200170448 cites W3042222104 @default.
- W4200170448 cites W3042866841 @default.
- W4200170448 cites W3045615676 @default.
- W4200170448 cites W3065103004 @default.
- W4200170448 cites W3090041485 @default.
- W4200170448 cites W3096978285 @default.
- W4200170448 cites W3097391371 @default.
- W4200170448 cites W3106009966 @default.
- W4200170448 cites W3118999257 @default.
- W4200170448 cites W3122921966 @default.
- W4200170448 cites W3127470950 @default.
- W4200170448 cites W3133377157 @default.
- W4200170448 cites W3135600405 @default.
- W4200170448 cites W3159323861 @default.
- W4200170448 cites W3173810740 @default.
- W4200170448 doi "https://doi.org/10.1016/j.cej.2021.134178" @default.
- W4200170448 hasPublicationYear "2022" @default.
- W4200170448 type Work @default.
- W4200170448 citedByCount "3" @default.
- W4200170448 countsByYear W42001704482022 @default.
- W4200170448 countsByYear W42001704482023 @default.
- W4200170448 crossrefType "journal-article" @default.
- W4200170448 hasAuthorship W4200170448A5005141691 @default.
- W4200170448 hasAuthorship W4200170448A5014528965 @default.
- W4200170448 hasAuthorship W4200170448A5016881517 @default.
- W4200170448 hasAuthorship W4200170448A5021906210 @default.
- W4200170448 hasAuthorship W4200170448A5032441946 @default.
- W4200170448 hasAuthorship W4200170448A5042103020 @default.
- W4200170448 hasAuthorship W4200170448A5071437727 @default.
- W4200170448 hasAuthorship W4200170448A5078040970 @default.
- W4200170448 hasConcept C104779481 @default.
- W4200170448 hasConcept C106487976 @default.
- W4200170448 hasConcept C127413603 @default.
- W4200170448 hasConcept C140205800 @default.
- W4200170448 hasConcept C159985019 @default.
- W4200170448 hasConcept C161790260 @default.
- W4200170448 hasConcept C163638829 @default.
- W4200170448 hasConcept C178790620 @default.
- W4200170448 hasConcept C185592680 @default.
- W4200170448 hasConcept C192562407 @default.
- W4200170448 hasConcept C2777581544 @default.
- W4200170448 hasConcept C36759035 @default.