Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200188751> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W4200188751 endingPage "25292" @default.
- W4200188751 startingPage "25286" @default.
- W4200188751 abstract "Abstract A new strategy to stabilize free radicals electronically is described by conjugating formally antiaromatic substituents to the free radical. With an antiaromatic substituent, the radical acts as an electron sink to allow configuration mixing of a low‐energy zwitterionic state that provides antiaromaticity relief to the substituent. A combination of X‐ray crystallography, VT‐EPR and VT‐UV/Vis spectroscopy, as well as computational analysis, was used to investigate this phenomenon. We find that this strategy of antiaromaticity relief is successful at stabilizing radicals, but only if the antiaromatic substituent is constrained to be planar by synthetically imposed conformational restraints that enable state mixing. This work leads to the counterintuitive finding that increasing the antiaromaticity of the radical substituent leads to greater radical stability, providing proof of concept for a new stereoelectronic approach for stabilizing free radicals." @default.
- W4200188751 created "2021-12-31" @default.
- W4200188751 creator A5006427207 @default.
- W4200188751 creator A5055368311 @default.
- W4200188751 creator A5065037360 @default.
- W4200188751 date "2021-10-13" @default.
- W4200188751 modified "2023-10-16" @default.
- W4200188751 title "Anti‐Aromaticity Relief as an Approach to Stabilize Free Radicals" @default.
- W4200188751 cites W1482232064 @default.
- W4200188751 cites W1968645088 @default.
- W4200188751 cites W1975171177 @default.
- W4200188751 cites W1977096237 @default.
- W4200188751 cites W1996061349 @default.
- W4200188751 cites W2032757769 @default.
- W4200188751 cites W2050791206 @default.
- W4200188751 cites W2064813419 @default.
- W4200188751 cites W2069251843 @default.
- W4200188751 cites W2079116676 @default.
- W4200188751 cites W2136284957 @default.
- W4200188751 cites W2170676330 @default.
- W4200188751 cites W2557764699 @default.
- W4200188751 cites W2611961442 @default.
- W4200188751 cites W2617365254 @default.
- W4200188751 cites W2646485970 @default.
- W4200188751 cites W2767266617 @default.
- W4200188751 cites W2768609528 @default.
- W4200188751 cites W2785276794 @default.
- W4200188751 cites W2901222351 @default.
- W4200188751 cites W2912316590 @default.
- W4200188751 cites W2932820136 @default.
- W4200188751 cites W2952952977 @default.
- W4200188751 cites W2972342190 @default.
- W4200188751 cites W2999938333 @default.
- W4200188751 cites W2999993848 @default.
- W4200188751 cites W3016396449 @default.
- W4200188751 cites W3125256525 @default.
- W4200188751 cites W4210800960 @default.
- W4200188751 cites W4211007953 @default.
- W4200188751 cites W4211182939 @default.
- W4200188751 cites W4229933734 @default.
- W4200188751 doi "https://doi.org/10.1002/ange.202110870" @default.
- W4200188751 hasPublicationYear "2021" @default.
- W4200188751 type Work @default.
- W4200188751 citedByCount "3" @default.
- W4200188751 countsByYear W42001887512022 @default.
- W4200188751 countsByYear W42001887512023 @default.
- W4200188751 crossrefType "journal-article" @default.
- W4200188751 hasAuthorship W4200188751A5006427207 @default.
- W4200188751 hasAuthorship W4200188751A5055368311 @default.
- W4200188751 hasAuthorship W4200188751A5065037360 @default.
- W4200188751 hasConcept C121332964 @default.
- W4200188751 hasConcept C139066938 @default.
- W4200188751 hasConcept C147597530 @default.
- W4200188751 hasConcept C178790620 @default.
- W4200188751 hasConcept C185592680 @default.
- W4200188751 hasConcept C187961010 @default.
- W4200188751 hasConcept C192386470 @default.
- W4200188751 hasConcept C2778689049 @default.
- W4200188751 hasConcept C32909587 @default.
- W4200188751 hasConcept C46141821 @default.
- W4200188751 hasConcept C55213715 @default.
- W4200188751 hasConcept C71240020 @default.
- W4200188751 hasConcept C75473681 @default.
- W4200188751 hasConceptScore W4200188751C121332964 @default.
- W4200188751 hasConceptScore W4200188751C139066938 @default.
- W4200188751 hasConceptScore W4200188751C147597530 @default.
- W4200188751 hasConceptScore W4200188751C178790620 @default.
- W4200188751 hasConceptScore W4200188751C185592680 @default.
- W4200188751 hasConceptScore W4200188751C187961010 @default.
- W4200188751 hasConceptScore W4200188751C192386470 @default.
- W4200188751 hasConceptScore W4200188751C2778689049 @default.
- W4200188751 hasConceptScore W4200188751C32909587 @default.
- W4200188751 hasConceptScore W4200188751C46141821 @default.
- W4200188751 hasConceptScore W4200188751C55213715 @default.
- W4200188751 hasConceptScore W4200188751C71240020 @default.
- W4200188751 hasConceptScore W4200188751C75473681 @default.
- W4200188751 hasFunder F4320337393 @default.
- W4200188751 hasIssue "47" @default.
- W4200188751 hasLocation W42001887511 @default.
- W4200188751 hasOpenAccess W4200188751 @default.
- W4200188751 hasPrimaryLocation W42001887511 @default.
- W4200188751 hasRelatedWork W1980154275 @default.
- W4200188751 hasRelatedWork W1983244813 @default.
- W4200188751 hasRelatedWork W1990000763 @default.
- W4200188751 hasRelatedWork W2063068258 @default.
- W4200188751 hasRelatedWork W2328794886 @default.
- W4200188751 hasRelatedWork W2902804733 @default.
- W4200188751 hasRelatedWork W3007820015 @default.
- W4200188751 hasRelatedWork W3186858347 @default.
- W4200188751 hasRelatedWork W4200188751 @default.
- W4200188751 hasRelatedWork W4362703658 @default.
- W4200188751 hasVolume "133" @default.
- W4200188751 isParatext "false" @default.
- W4200188751 isRetracted "false" @default.
- W4200188751 workType "article" @default.