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- W4200201875 abstract "Herein, a novel and facile dual-wavelength ratiometric electrochemiluminescence-resonance energy transfer (ECL-RET) sensor for hydrogen sulfide (H2S) detection was constructed based on the interaction between S2- and Cd2+-doped g-C3N4 nanosheets (NSs). Cd2+-doped g-C3N4 NSs exhibited a strong ECL emission at 435 nm. In the presence of H2S, CdS was formed in situ on g-C3N4 NSs by the adsorption of S2- and Cd2+, generating another ECL emission at 515 nm. Furthermore, the overlapping of the absorption spectrum of the formed CdS and the ECL emission spectrum of g-C3N4 NSs led to a feasible RET, thus quenching the ECL intensity from g-C3N4 at 435 nm. Through an ECL decrease at 435 nm and an increase at 515 nm, a dual-wavelength ratiometric ECL-RET system for H2S was designed. The sensor exhibited a lower detection limit of 0.02 μM with a wide linear range of 0.05-100.0 μM. In addition, the applicability of the method was validated by plasma sample analysis with a linear range of 80.0-106.0%. We believe that such a proposal would provide new insight into advanced dual-wavelength ECL ratiometric assays." @default.
- W4200201875 created "2021-12-31" @default.
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- W4200201875 date "2022-01-01" @default.
- W4200201875 modified "2023-10-12" @default.
- W4200201875 title "Dual-wavelength electrochemiluminescence ratiometry for hydrogen sulfide detection based on Cd<sup>2+</sup>-doped g-C<sub>3</sub>N<sub>4</sub> nanosheets" @default.
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- W4200201875 doi "https://doi.org/10.1039/d1an01873f" @default.
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