Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200203695> ?p ?o ?g. }
- W4200203695 endingPage "705" @default.
- W4200203695 startingPage "700" @default.
- W4200203695 abstract "It is common knowledge that metal-to-ligand π back-donation requires filled atomic orbitals at the metal center. However, we show through a combined experimental and theoretical approach that Be(II)→N-heterocyclic carbene (NHC) π back-donation is present in the two carbene adducts [(iPr)BeBr2] (1) and [(iPr)2BeBr2] (2) (iPr = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene). These complexes were characterized with NMR, IR, and Raman spectroscopy as well as with single-crystal X-ray diffractometry. The unusual bonding situation is understood from the results of energy decomposition analysis in combination with natural orbital for chemical valence and quantum theory of atoms-in-molecules analysis. The obtained findings shed light on the unusually high Be-C bond strength in carbene adducts to beryllium compounds and rationalize their geometry and reactivity." @default.
- W4200203695 created "2021-12-31" @default.
- W4200203695 creator A5024805893 @default.
- W4200203695 creator A5026006704 @default.
- W4200203695 creator A5033413160 @default.
- W4200203695 creator A5040103094 @default.
- W4200203695 creator A5061697577 @default.
- W4200203695 date "2021-12-13" @default.
- W4200203695 modified "2023-10-13" @default.
- W4200203695 title "π Back-Donation from a Beryllium Dibromide Fragment at the Expense of Its σ Strength" @default.
- W4200203695 cites W1998554892 @default.
- W4200203695 cites W2018204717 @default.
- W4200203695 cites W2018324673 @default.
- W4200203695 cites W2023045222 @default.
- W4200203695 cites W2066607597 @default.
- W4200203695 cites W2081098918 @default.
- W4200203695 cites W2087379598 @default.
- W4200203695 cites W2123076640 @default.
- W4200203695 cites W2163844500 @default.
- W4200203695 cites W2409147736 @default.
- W4200203695 cites W2469994215 @default.
- W4200203695 cites W2510079115 @default.
- W4200203695 cites W2604156473 @default.
- W4200203695 cites W2756328360 @default.
- W4200203695 cites W2808116542 @default.
- W4200203695 cites W2811352597 @default.
- W4200203695 cites W2883754955 @default.
- W4200203695 cites W2901897556 @default.
- W4200203695 cites W2911345469 @default.
- W4200203695 cites W2945497586 @default.
- W4200203695 cites W2948760799 @default.
- W4200203695 cites W2951402723 @default.
- W4200203695 cites W2985322110 @default.
- W4200203695 cites W3000577799 @default.
- W4200203695 cites W3008395880 @default.
- W4200203695 cites W3011786271 @default.
- W4200203695 cites W3012377587 @default.
- W4200203695 cites W3021481835 @default.
- W4200203695 cites W3036420596 @default.
- W4200203695 cites W3037747151 @default.
- W4200203695 cites W3080525802 @default.
- W4200203695 cites W3101413608 @default.
- W4200203695 cites W3119610205 @default.
- W4200203695 cites W3161646499 @default.
- W4200203695 cites W3182951708 @default.
- W4200203695 doi "https://doi.org/10.1021/acs.inorgchem.1c03449" @default.
- W4200203695 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34894684" @default.
- W4200203695 hasPublicationYear "2021" @default.
- W4200203695 type Work @default.
- W4200203695 citedByCount "10" @default.
- W4200203695 countsByYear W42002036952022 @default.
- W4200203695 countsByYear W42002036952023 @default.
- W4200203695 crossrefType "journal-article" @default.
- W4200203695 hasAuthorship W4200203695A5024805893 @default.
- W4200203695 hasAuthorship W4200203695A5026006704 @default.
- W4200203695 hasAuthorship W4200203695A5033413160 @default.
- W4200203695 hasAuthorship W4200203695A5040103094 @default.
- W4200203695 hasAuthorship W4200203695A5061697577 @default.
- W4200203695 hasConcept C108204754 @default.
- W4200203695 hasConcept C116569031 @default.
- W4200203695 hasConcept C120665830 @default.
- W4200203695 hasConcept C121332964 @default.
- W4200203695 hasConcept C130188946 @default.
- W4200203695 hasConcept C142724271 @default.
- W4200203695 hasConcept C147120987 @default.
- W4200203695 hasConcept C147597530 @default.
- W4200203695 hasConcept C161790260 @default.
- W4200203695 hasConcept C168900304 @default.
- W4200203695 hasConcept C170493617 @default.
- W4200203695 hasConcept C178790620 @default.
- W4200203695 hasConcept C185592680 @default.
- W4200203695 hasConcept C189394030 @default.
- W4200203695 hasConcept C204787440 @default.
- W4200203695 hasConcept C2776910235 @default.
- W4200203695 hasConcept C2777164566 @default.
- W4200203695 hasConcept C32909587 @default.
- W4200203695 hasConcept C40003534 @default.
- W4200203695 hasConcept C506630978 @default.
- W4200203695 hasConcept C55493867 @default.
- W4200203695 hasConcept C62520636 @default.
- W4200203695 hasConcept C71924100 @default.
- W4200203695 hasConcept C8010536 @default.
- W4200203695 hasConceptScore W4200203695C108204754 @default.
- W4200203695 hasConceptScore W4200203695C116569031 @default.
- W4200203695 hasConceptScore W4200203695C120665830 @default.
- W4200203695 hasConceptScore W4200203695C121332964 @default.
- W4200203695 hasConceptScore W4200203695C130188946 @default.
- W4200203695 hasConceptScore W4200203695C142724271 @default.
- W4200203695 hasConceptScore W4200203695C147120987 @default.
- W4200203695 hasConceptScore W4200203695C147597530 @default.
- W4200203695 hasConceptScore W4200203695C161790260 @default.
- W4200203695 hasConceptScore W4200203695C168900304 @default.
- W4200203695 hasConceptScore W4200203695C170493617 @default.
- W4200203695 hasConceptScore W4200203695C178790620 @default.
- W4200203695 hasConceptScore W4200203695C185592680 @default.
- W4200203695 hasConceptScore W4200203695C189394030 @default.
- W4200203695 hasConceptScore W4200203695C204787440 @default.
- W4200203695 hasConceptScore W4200203695C2776910235 @default.