Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200207894> ?p ?o ?g. }
Showing items 1 to 90 of
90
with 100 items per page.
- W4200207894 abstract "Abstract Dioximes as ligands are used as analytical reagents and serve as models for biological systems as well as catalysts in chemical processes. A number of novel mixed complexes of the type [Fe(DioxH) 2 (amine) 2 ] have been prepared and characterised by FTIR, 57 Fe Mössbauer and mass spectroscopy by us. We have found strong Fe–N donor acceptor interactions and iron occurred in low-spin Fe II state in all complexes. Later, we have also found that the incorporation of branching alkyl chains (isopropyl) in the complexes alters the Fe–N bond length and results in high-spin iron(II) state [1, 2]. The question arises: can the spin state of iron be manipulated generally by replacing the short alkyl chains with high volume demand ones in Fe-azomethine-amine complexes? To answer the question we have synthetized novel iron-bis-glioxime and iron-tris-gloxime complexes when long chain alkyl or aromatic ligands replaced the short alkyl ones and studied by 57 Fe Mössbauer spectroscopy, MS, FTIR, UV-VIS, TG-DTA-DTG and XRD methods. Novel iron-bis-glyoxime and iron-tris-glyoxime type complexes, [Fe(Diethyl-Diox) 3 (BOH) 2 ], [Fe(Diethyl-Diox) 3 (BOEt) 2 ] and [Fe(phenyl-Me-Diox) 3 (BOEt) 2 ], were synthesized similarly as described in [2]. The FTIR, UV-VIS, TG-DTA-DTG and MS measurements indicated that the expected novel complexes could be successfully synthesized." @default.
- W4200207894 created "2021-12-31" @default.
- W4200207894 creator A5006776892 @default.
- W4200207894 creator A5011654925 @default.
- W4200207894 creator A5020288042 @default.
- W4200207894 creator A5033750639 @default.
- W4200207894 creator A5042664040 @default.
- W4200207894 creator A5074767653 @default.
- W4200207894 creator A5077186440 @default.
- W4200207894 creator A5079631797 @default.
- W4200207894 creator A5085420817 @default.
- W4200207894 creator A5086789662 @default.
- W4200207894 creator A5091174332 @default.
- W4200207894 date "2021-12-30" @default.
- W4200207894 modified "2023-10-18" @default.
- W4200207894 title "Mössbauer study of some novel iron-bis-glyoxime and iron-tris-glyoxime complexes" @default.
- W4200207894 cites W1973679358 @default.
- W4200207894 cites W2017328271 @default.
- W4200207894 cites W2065485344 @default.
- W4200207894 cites W2073943050 @default.
- W4200207894 cites W2102765106 @default.
- W4200207894 cites W2109349559 @default.
- W4200207894 doi "https://doi.org/10.1007/s10751-021-01738-2" @default.
- W4200207894 hasPublicationYear "2021" @default.
- W4200207894 type Work @default.
- W4200207894 citedByCount "1" @default.
- W4200207894 countsByYear W42002078942022 @default.
- W4200207894 crossrefType "journal-article" @default.
- W4200207894 hasAuthorship W4200207894A5006776892 @default.
- W4200207894 hasAuthorship W4200207894A5011654925 @default.
- W4200207894 hasAuthorship W4200207894A5020288042 @default.
- W4200207894 hasAuthorship W4200207894A5033750639 @default.
- W4200207894 hasAuthorship W4200207894A5042664040 @default.
- W4200207894 hasAuthorship W4200207894A5074767653 @default.
- W4200207894 hasAuthorship W4200207894A5077186440 @default.
- W4200207894 hasAuthorship W4200207894A5079631797 @default.
- W4200207894 hasAuthorship W4200207894A5085420817 @default.
- W4200207894 hasAuthorship W4200207894A5086789662 @default.
- W4200207894 hasAuthorship W4200207894A5091174332 @default.
- W4200207894 hasBestOaLocation W42002078941 @default.
- W4200207894 hasConcept C104264131 @default.
- W4200207894 hasConcept C121332964 @default.
- W4200207894 hasConcept C131779359 @default.
- W4200207894 hasConcept C155647269 @default.
- W4200207894 hasConcept C160892712 @default.
- W4200207894 hasConcept C178790620 @default.
- W4200207894 hasConcept C179104552 @default.
- W4200207894 hasConcept C185592680 @default.
- W4200207894 hasConcept C188027245 @default.
- W4200207894 hasConcept C2780263894 @default.
- W4200207894 hasConcept C2781014771 @default.
- W4200207894 hasConcept C55493867 @default.
- W4200207894 hasConcept C62520636 @default.
- W4200207894 hasConcept C70854507 @default.
- W4200207894 hasConcept C8010536 @default.
- W4200207894 hasConceptScore W4200207894C104264131 @default.
- W4200207894 hasConceptScore W4200207894C121332964 @default.
- W4200207894 hasConceptScore W4200207894C131779359 @default.
- W4200207894 hasConceptScore W4200207894C155647269 @default.
- W4200207894 hasConceptScore W4200207894C160892712 @default.
- W4200207894 hasConceptScore W4200207894C178790620 @default.
- W4200207894 hasConceptScore W4200207894C179104552 @default.
- W4200207894 hasConceptScore W4200207894C185592680 @default.
- W4200207894 hasConceptScore W4200207894C188027245 @default.
- W4200207894 hasConceptScore W4200207894C2780263894 @default.
- W4200207894 hasConceptScore W4200207894C2781014771 @default.
- W4200207894 hasConceptScore W4200207894C55493867 @default.
- W4200207894 hasConceptScore W4200207894C62520636 @default.
- W4200207894 hasConceptScore W4200207894C70854507 @default.
- W4200207894 hasConceptScore W4200207894C8010536 @default.
- W4200207894 hasFunder F4320326124 @default.
- W4200207894 hasIssue "1" @default.
- W4200207894 hasLocation W42002078941 @default.
- W4200207894 hasLocation W42002078942 @default.
- W4200207894 hasOpenAccess W4200207894 @default.
- W4200207894 hasPrimaryLocation W42002078941 @default.
- W4200207894 hasRelatedWork W1989507448 @default.
- W4200207894 hasRelatedWork W2095002423 @default.
- W4200207894 hasRelatedWork W2109349559 @default.
- W4200207894 hasRelatedWork W2292811770 @default.
- W4200207894 hasRelatedWork W2324898221 @default.
- W4200207894 hasRelatedWork W2403608485 @default.
- W4200207894 hasRelatedWork W2607320909 @default.
- W4200207894 hasRelatedWork W2953193372 @default.
- W4200207894 hasRelatedWork W2953235637 @default.
- W4200207894 hasRelatedWork W3137909308 @default.
- W4200207894 hasVolume "243" @default.
- W4200207894 isParatext "false" @default.
- W4200207894 isRetracted "false" @default.
- W4200207894 workType "article" @default.