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- W4200212997 abstract "Cycloaddition of metallo-vinylcarbenes is an intramolecular combination of the three carbon atoms of a metal vinylcarbene with the carbon of a carbenoid donor or the nitrogen of a nitrenoid donor in a [3+1]-cycloaddition or with an unsaturated molecule or a dipolar species in a [3+ n ]-cycloaddition. As the newest class of metal carbene transformations and occurring as a two-step process of addition–elimination, cycloaddition offers diverse access to carbocyclic and heterocyclic compounds in high yields with remarkable diastereocontrol and enantioselectivity. Its rapid development is due to the unique characteristics of silyl-protected enoldiazo-carbonyl and -sulfonyl compounds that have also provided access to donor–acceptor cyclopropenes for alternative access to metallo-vinylcarbenes. Chiral dirhodium(II) carboxylates, especially those with amino acid phthalimide ligands, and cationic copper(I) complexes with Box and SaBox ligands are the most effective and selective catalysts." @default.
- W4200212997 created "2021-12-31" @default.
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- W4200212997 date "2021-12-24" @default.
- W4200212997 modified "2023-09-25" @default.
- W4200212997 title "Metal Carbene Cycloaddition Reactions" @default.
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- W4200212997 doi "https://doi.org/10.1002/9783527829170.ch5" @default.
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