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- W4200217085 abstract "Carboranes are a class of polyhedral boron-carbon molecular clusters, they can serve as versatile ligands in stabilizing low-valent main group element compounds, due to their exceptionally thermal and chemical stabilities, easy modifications at the cage carbon vertices, as well as large spherical steric effects. These carborane-based ligands provide interesting opportunities for the synthesis of low-valent main group element compounds with novel structure and reactivity, which indeed enrich the chemistry of low-valent element main group compounds. This review summarizes the recent advances in the chemistry of low-valent group 13 and group 14 element compounds supported by carborane-based ligands. Achievements and perspectives in this new and flourishing field are discussed in this review. A review of recent achievements on carborane-based ligands in low-valent group 13 and group 14 elements chemistry, mainly focus on their synthesis, structure and reactivity." @default.
- W4200217085 created "2021-12-31" @default.
- W4200217085 creator A5054041103 @default.
- W4200217085 date "2022-08-01" @default.
- W4200217085 modified "2023-09-25" @default.
- W4200217085 title "Recent advances on carborane-based ligands in low-valent group 13 and group 14 elements chemistry" @default.
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- W4200217085 doi "https://doi.org/10.1016/j.cclet.2021.12.016" @default.
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