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- W4200219009 abstract "We have investigated the nature and extent of nanoscale disorder in prototypical host–guest zeolites, made of silicalite-1 (host) and organic structure-directing agent (OSDA, guest). The four different selected OSDA-silicalite-1 differ in: the mineralizing agent used (F– vs OH–), the synthesis method (hydrothermal vs solvent-free), and the OSDA (tetrapropylammonium (TPA) vs tripropylethylammonium TPEA). The comparison between TPA and TPEA, chemically similar but differing in their symmetry, is examined in great detail owing to the novel relationship found between the geometrical disorder and the monoclinic–orthorhombic (m–o) phase transition occurring at low temperatures. Long- and short-range organization and ordering are characterized by complementary X-ray diffraction (XRD), Raman analysis, and multinuclear NMR spectroscopy (13C, 14N, 29Si). The possibility of the m–o transition is studied by all of these techniques at variable low T values. An in-depth study of the disorder is carried out by X-ray structure determination and two-dimensional (2D) NMR 29Si–29Si INADEQUATE correlations, including an up-to-date analysis of anisotropic atomic displacement parameters and a new fitting approach to estimate correlated disorder from 2D NMR data sets. The collected results allow us to demonstrate how the disorder created by the positioning of the less symmetric TPEA guest leads to a correlated geometrical disorder for half of the atom sites in the host framework that completely inhibits the m–o phase transition." @default.
- W4200219009 created "2021-12-31" @default.
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- W4200219009 date "2021-12-30" @default.
- W4200219009 modified "2023-10-12" @default.
- W4200219009 title "Host–Guest Silicalite-1 Zeolites: Correlated Disorder and Phase Transition Inhibition by a Small Guest Modification" @default.
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