FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200260768> ?p ?o ?g. }

• W4200260768 endingPage "623" @default.
• W4200260768 startingPage "614" @default.
• W4200260768 abstract "Electrocatalytic nitrate (NO3-) reduction to N2 via atomic hydrogen (H*) is a promising approach for advanced water treatment. However, the reduction rate and N2 selectivity are hindered by slow mass transfer and H* provision-utilization mismatch, respectively. Herein, we report an open-framework cathode bearing electron-rich Co sites with extraordinary H* provision performance, which was validated by electron spin resonance (ESR) and cyclic voltammetry (CV) tests. Benefiting from its abundant channels, NO3- has a greater opportunity to be efficiently transferred to the vicinity of the Co active sites. Owing to the enhanced mass transfer and on-demand H* provision, the nitrate removal efficiency and N2 selectivity of the proposed cathode were 100 and 97.89%, respectively, superior to those of noble metal-based electrodes. In addition, in situ differential electrochemical mass spectrometry (DEMS) indicated that ultrafast *NO2- to *NO reduction and highly selective *NO to *N2O or *N transformation played crucial roles during the NO3- reduction process. Moreover, the proposed electrochemical system can achieve remarkable N2 selectivity without the additional Cl- supply, thus avoiding the formation of chlorinated byproducts, which are usually observed in conventional electrochemical nitrate reduction processes. Environmentally, energy conservation and negligible byproduct release ensure its practicability for use in nitrate remediation." @default.
• W4200260768 created "2021-12-31" @default.
• W4200260768 creator A5017972217 @default.
• W4200260768 creator A5031383697 @default.
• W4200260768 creator A5044963278 @default.
• W4200260768 creator A5060461853 @default.
• W4200260768 date "2021-12-16" @default.
• W4200260768 modified "2023-10-11" @default.
• W4200260768 title "On-Demand Atomic Hydrogen Provision by Exposing Electron-Rich Cobalt Sites in an Open-Framework Structure toward Superior Electrocatalytic Nitrate Conversion to Dinitrogen" @default.
• W4200260768 cites W1956694005 @default.
• W4200260768 cites W1981921533 @default.
• W4200260768 cites W1983606260 @default.
• W4200260768 cites W1992867482 @default.
• W4200260768 cites W2037991945 @default.
• W4200260768 cites W2039102726 @default.
• W4200260768 cites W2059682795 @default.
• W4200260768 cites W2066623343 @default.
• W4200260768 cites W2074894104 @default.
• W4200260768 cites W2086270926 @default.
• W4200260768 cites W2114042821 @default.
• W4200260768 cites W2147592121 @default.
• W4200260768 cites W2195521325 @default.
• W4200260768 cites W2298591544 @default.
• W4200260768 cites W2313383469 @default.
• W4200260768 cites W2315137224 @default.
• W4200260768 cites W2555979001 @default.
• W4200260768 cites W2586571084 @default.
• W4200260768 cites W2608294287 @default.
• W4200260768 cites W2609506109 @default.
• W4200260768 cites W2613194023 @default.
• W4200260768 cites W2617656420 @default.
• W4200260768 cites W2769336413 @default.
• W4200260768 cites W2772819232 @default.
• W4200260768 cites W2774628153 @default.
• W4200260768 cites W2787875306 @default.
• W4200260768 cites W2803724286 @default.
• W4200260768 cites W2884175952 @default.
• W4200260768 cites W2885736519 @default.
• W4200260768 cites W2886852674 @default.
• W4200260768 cites W2889634968 @default.
• W4200260768 cites W2908244383 @default.
• W4200260768 cites W2913494786 @default.
• W4200260768 cites W2914891249 @default.
• W4200260768 cites W2933691242 @default.
• W4200260768 cites W2936448275 @default.
• W4200260768 cites W2939584566 @default.
• W4200260768 cites W2947493209 @default.
• W4200260768 cites W2953681281 @default.
• W4200260768 cites W2964688816 @default.
• W4200260768 cites W2971676432 @default.
• W4200260768 cites W2978073583 @default.
• W4200260768 cites W2978588766 @default.
• W4200260768 cites W2993882915 @default.
• W4200260768 cites W2998473339 @default.
• W4200260768 cites W3001919290 @default.
• W4200260768 cites W3008458849 @default.
• W4200260768 cites W3010349983 @default.
• W4200260768 cites W3037254992 @default.
• W4200260768 cites W3047840007 @default.
• W4200260768 cites W3080463758 @default.
• W4200260768 cites W3082527738 @default.
• W4200260768 cites W3089768671 @default.
• W4200260768 cites W3092079676 @default.
• W4200260768 cites W3095821895 @default.
• W4200260768 cites W3096690810 @default.
• W4200260768 cites W3101519145 @default.
• W4200260768 cites W3112870018 @default.
• W4200260768 cites W3119925172 @default.
• W4200260768 cites W3126331808 @default.
• W4200260768 cites W3130316211 @default.
• W4200260768 cites W3130708786 @default.
• W4200260768 cites W3134446032 @default.
• W4200260768 cites W3164163552 @default.
• W4200260768 cites W3173728042 @default.
• W4200260768 cites W4289024938 @default.
• W4200260768 doi "https://doi.org/10.1021/acs.est.1c06091" @default.
• W4200260768 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34914357" @default.
• W4200260768 hasPublicationYear "2021" @default.
• W4200260768 type Work @default.
• W4200260768 citedByCount "47" @default.
• W4200260768 countsByYear W42002607682022 @default.
• W4200260768 countsByYear W42002607682023 @default.
• W4200260768 crossrefType "journal-article" @default.
• W4200260768 hasAuthorship W4200260768A5017972217 @default.
• W4200260768 hasAuthorship W4200260768A5031383697 @default.
• W4200260768 hasAuthorship W4200260768A5044963278 @default.
• W4200260768 hasAuthorship W4200260768A5060461853 @default.
• W4200260768 hasConcept C118792377 @default.
• W4200260768 hasConcept C123669783 @default.
• W4200260768 hasConcept C147789679 @default.
• W4200260768 hasConcept C161790260 @default.
• W4200260768 hasConcept C17525397 @default.
• W4200260768 hasConcept C178790620 @default.
• W4200260768 hasConcept C179104552 @default.
• W4200260768 hasConcept C185592680 @default.
• W4200260768 hasConcept C2776384668 @default.
• W4200260768 hasConcept C2777869211 @default.
• W4200260768 hasConcept C49110097 @default.

• next