Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200268045> ?p ?o ?g. }
- W4200268045 endingPage "1484" @default.
- W4200268045 startingPage "1484" @default.
- W4200268045 abstract "Perovskite-type oxides are highly flexible materials that show properties that are beneficial for application in reverse water-gas shift processes (rWGS). Due to their stable nature, the ability to incorporate catalytically active dopants in their lattice structure, and the corresponding feature of nanoparticle exsolution, they are promising candidates for a materials design approach. On an industrial level, the rWGS has proven to be an excellent choice for the efficient utilisation of CO2 as an abundant and renewable carbon source, reflected by the current research on novel and improved catalyst materials. In the current study, a correlation between rWGS reaction environments (CO2 to H2 ratios and temperature), surface morphology, and catalytic activity of three perovskite catalysts (Nd0.6Ca0.4Fe0.9Co0.1O3-δ, Nd0.6Ca0.4Fe0.97Co0.03O3-δ, and Nd0.6Ca0.4Fe0.97Ni0.03O3-δ) is investigated, combining catalytic measurements with SEM and NAP-XPS. The materials were found to react dynamically to the conditions showing both activation due to in situ nanoparticle exsolution and deactivation via CaCO3 formation. This phenomenon could be influenced by choice of material and conditions: less reductive conditions (larger CO2 to H2 or lower temperature) lead to smaller exsolved particles and reduced carbonate formation. However, the B-site doping was also important; only with 10% Co-doping, a predominant activation could be achieved." @default.
- W4200268045 created "2021-12-31" @default.
- W4200268045 creator A5016170695 @default.
- W4200268045 creator A5018511924 @default.
- W4200268045 creator A5033692248 @default.
- W4200268045 creator A5039818381 @default.
- W4200268045 creator A5066467119 @default.
- W4200268045 creator A5074136841 @default.
- W4200268045 creator A5087899046 @default.
- W4200268045 creator A5089460517 @default.
- W4200268045 date "2021-12-03" @default.
- W4200268045 modified "2023-10-10" @default.
- W4200268045 title "In Situ Growth of Exsolved Nanoparticles under Varying rWGS Reaction Conditions—A Catalysis and Near Ambient Pressure-XPS Study" @default.
- W4200268045 cites W1975197646 @default.
- W4200268045 cites W1989319638 @default.
- W4200268045 cites W1991630775 @default.
- W4200268045 cites W1995239906 @default.
- W4200268045 cites W2007117531 @default.
- W4200268045 cites W2012585746 @default.
- W4200268045 cites W2040755679 @default.
- W4200268045 cites W2041126800 @default.
- W4200268045 cites W2044358811 @default.
- W4200268045 cites W2051469691 @default.
- W4200268045 cites W2059795417 @default.
- W4200268045 cites W2064039635 @default.
- W4200268045 cites W2073466472 @default.
- W4200268045 cites W2076797523 @default.
- W4200268045 cites W2085275777 @default.
- W4200268045 cites W2087727728 @default.
- W4200268045 cites W2098547240 @default.
- W4200268045 cites W2123134406 @default.
- W4200268045 cites W2124455426 @default.
- W4200268045 cites W2125720063 @default.
- W4200268045 cites W2134636810 @default.
- W4200268045 cites W2135625048 @default.
- W4200268045 cites W2151003469 @default.
- W4200268045 cites W2152083949 @default.
- W4200268045 cites W2154304209 @default.
- W4200268045 cites W2167056627 @default.
- W4200268045 cites W2167279371 @default.
- W4200268045 cites W2176074737 @default.
- W4200268045 cites W2180858213 @default.
- W4200268045 cites W2321165180 @default.
- W4200268045 cites W2322976541 @default.
- W4200268045 cites W2326772021 @default.
- W4200268045 cites W2327215041 @default.
- W4200268045 cites W2334931225 @default.
- W4200268045 cites W2342966047 @default.
- W4200268045 cites W2345600217 @default.
- W4200268045 cites W2465806986 @default.
- W4200268045 cites W2468221265 @default.
- W4200268045 cites W2494012753 @default.
- W4200268045 cites W2529492055 @default.
- W4200268045 cites W2549757335 @default.
- W4200268045 cites W2603263016 @default.
- W4200268045 cites W2755919341 @default.
- W4200268045 cites W2757448584 @default.
- W4200268045 cites W2767331214 @default.
- W4200268045 cites W2783980283 @default.
- W4200268045 cites W2794824452 @default.
- W4200268045 cites W2804368987 @default.
- W4200268045 cites W2804777226 @default.
- W4200268045 cites W2888532099 @default.
- W4200268045 cites W2902840813 @default.
- W4200268045 cites W2931660935 @default.
- W4200268045 cites W2981195899 @default.
- W4200268045 cites W2998324234 @default.
- W4200268045 cites W2998445976 @default.
- W4200268045 cites W3009159365 @default.
- W4200268045 cites W3018760218 @default.
- W4200268045 cites W3033381215 @default.
- W4200268045 cites W3039722283 @default.
- W4200268045 cites W3092887220 @default.
- W4200268045 cites W3109897314 @default.
- W4200268045 cites W3130312945 @default.
- W4200268045 cites W3148035161 @default.
- W4200268045 doi "https://doi.org/10.3390/catal11121484" @default.
- W4200268045 hasPublicationYear "2021" @default.
- W4200268045 type Work @default.
- W4200268045 citedByCount "5" @default.
- W4200268045 countsByYear W42002680452022 @default.
- W4200268045 countsByYear W42002680452023 @default.
- W4200268045 crossrefType "journal-article" @default.
- W4200268045 hasAuthorship W4200268045A5016170695 @default.
- W4200268045 hasAuthorship W4200268045A5018511924 @default.
- W4200268045 hasAuthorship W4200268045A5033692248 @default.
- W4200268045 hasAuthorship W4200268045A5039818381 @default.
- W4200268045 hasAuthorship W4200268045A5066467119 @default.
- W4200268045 hasAuthorship W4200268045A5074136841 @default.
- W4200268045 hasAuthorship W4200268045A5087899046 @default.
- W4200268045 hasAuthorship W4200268045A5089460517 @default.
- W4200268045 hasBestOaLocation W42002680451 @default.
- W4200268045 hasConcept C127413603 @default.
- W4200268045 hasConcept C155672457 @default.
- W4200268045 hasConcept C161790260 @default.
- W4200268045 hasConcept C171250308 @default.
- W4200268045 hasConcept C175708663 @default.
- W4200268045 hasConcept C178790620 @default.