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- W4200277526 endingPage "157" @default.
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- W4200277526 abstract "A general synthetic entry to functionalized dihydrophenalenes has been found using naphthyl-cyclopropane esters as starting materials. The desired annulation was possible with visible light, Ir(Fppy)3 as photocatalyst, BnNMe2 or DABCO as electron donor, HAT-catalyst, and proton source. A broad scope of substituted naphthyl and azanaphthyl derivatives provided the photoannulation products in high yield. Deuteration studies support a photoredox mechanism involving the photoreductive cyclopropane opening to an enolate radical followed by an aryl radical trapping." @default.
- W4200277526 created "2021-12-31" @default.
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- W4200277526 creator A5057978605 @default.
- W4200277526 date "2021-12-21" @default.
- W4200277526 modified "2023-09-24" @default.
- W4200277526 title "Visible-Light-Induced Photoannulation of α-Naphthyl Cyclopropane Carboxylic Esters to Functionalized Dihydrophenalenes" @default.
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- W4200277526 doi "https://doi.org/10.1021/acs.orglett.1c03784" @default.
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