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- W4200282368 endingPage "1040" @default.
- W4200282368 startingPage "1031" @default.
- W4200282368 abstract "The development of heterogeneous, chemoselective, and tandem catalytic systems using abundant metals is vital for the sustainable synthesis of fine and commodity chemicals. We report a robust and recyclable single-site cobalt-hydride catalyst based on a porous aluminum metal-organic framework (DUT-5 MOF) for chemoselective hydrogenation of arenes. The DUT-5 node-supported cobalt(II) hydride (DUT-5-CoH) is a versatile solid catalyst for chemoselective hydrogenation of a range of nonpolar and polar arenes, including heteroarenes such as pyridines, quinolines, isoquinolines, indoles, and furans to afford cycloalkanes and saturated heterocycles in excellent yields. DUT-5-CoH exhibited excellent functional group tolerance and could be reusable at least five times without decreased activity. The same MOF-Co catalyst was also efficient for tandem hydrogenation-hydrodeoxygenation of aryl carbonyl compounds, including biomass-derived platform molecules such as furfural and hydroxymethylfurfural to cycloalkanes. In the case of hydrogenation of cumene, our spectroscopic, kinetic, and density functional theory (DFT) studies suggest the insertion of a trisubstituted alkene intermediate into the Co-H bond occurring in the turnover limiting step. Our work highlights the potential of MOF-supported single-site base-metal catalysts for sustainable and environment-friendly industrial production of chemicals and biofuels." @default.
- W4200282368 created "2021-12-31" @default.
- W4200282368 creator A5012637212 @default.
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- W4200282368 creator A5075862321 @default.
- W4200282368 date "2021-12-30" @default.
- W4200282368 modified "2023-10-16" @default.
- W4200282368 title "Chemoselective and Tandem Reduction of Arenes Using a Metal–Organic Framework-Supported Single-Site Cobalt Catalyst" @default.
- W4200282368 cites W170187654 @default.
- W4200282368 cites W1970622333 @default.
- W4200282368 cites W1974404404 @default.
- W4200282368 cites W1976655642 @default.
- W4200282368 cites W1982907022 @default.
- W4200282368 cites W1988731900 @default.
- W4200282368 cites W1990250040 @default.
- W4200282368 cites W1993141256 @default.
- W4200282368 cites W1993491755 @default.
- W4200282368 cites W1995538236 @default.
- W4200282368 cites W2005495998 @default.
- W4200282368 cites W2007082361 @default.
- W4200282368 cites W2010422626 @default.
- W4200282368 cites W2028935067 @default.
- W4200282368 cites W2034734953 @default.
- W4200282368 cites W203845114 @default.
- W4200282368 cites W2041114633 @default.
- W4200282368 cites W2041537180 @default.
- W4200282368 cites W2051191132 @default.
- W4200282368 cites W2059337426 @default.
- W4200282368 cites W2063947896 @default.
- W4200282368 cites W2064311631 @default.
- W4200282368 cites W2068249614 @default.
- W4200282368 cites W2079257415 @default.
- W4200282368 cites W2082507193 @default.
- W4200282368 cites W2094668165 @default.
- W4200282368 cites W2105416864 @default.
- W4200282368 cites W2108448217 @default.
- W4200282368 cites W2110095922 @default.
- W4200282368 cites W2110730693 @default.
- W4200282368 cites W2124810596 @default.
- W4200282368 cites W2126676230 @default.
- W4200282368 cites W2141939342 @default.
- W4200282368 cites W2155714497 @default.
- W4200282368 cites W2166846501 @default.
- W4200282368 cites W2172200203 @default.
- W4200282368 cites W2238889153 @default.
- W4200282368 cites W2260759476 @default.
- W4200282368 cites W2265503716 @default.
- W4200282368 cites W2271419034 @default.
- W4200282368 cites W2283564633 @default.
- W4200282368 cites W2292460150 @default.
- W4200282368 cites W2299040464 @default.
- W4200282368 cites W2302759951 @default.
- W4200282368 cites W2328070910 @default.
- W4200282368 cites W2330227554 @default.
- W4200282368 cites W2333296790 @default.
- W4200282368 cites W2333890779 @default.
- W4200282368 cites W2343511638 @default.
- W4200282368 cites W2407040666 @default.
- W4200282368 cites W2412087944 @default.
- W4200282368 cites W2418077897 @default.
- W4200282368 cites W2461100487 @default.
- W4200282368 cites W2489627648 @default.
- W4200282368 cites W2513328261 @default.
- W4200282368 cites W2515275952 @default.
- W4200282368 cites W2562044353 @default.
- W4200282368 cites W2567277011 @default.
- W4200282368 cites W2588857630 @default.
- W4200282368 cites W2590688100 @default.
- W4200282368 cites W2617286961 @default.
- W4200282368 cites W2744291776 @default.
- W4200282368 cites W2747844706 @default.
- W4200282368 cites W2766311670 @default.
- W4200282368 cites W2772899329 @default.
- W4200282368 cites W2793422627 @default.
- W4200282368 cites W2796643448 @default.
- W4200282368 cites W2800520754 @default.
- W4200282368 cites W2809133580 @default.
- W4200282368 cites W2887841258 @default.
- W4200282368 cites W2888652040 @default.
- W4200282368 cites W2889636613 @default.
- W4200282368 cites W2891315435 @default.
- W4200282368 cites W2897174423 @default.
- W4200282368 cites W2902391378 @default.
- W4200282368 cites W2904951766 @default.
- W4200282368 cites W2911098092 @default.
- W4200282368 cites W2921568354 @default.
- W4200282368 cites W2952222036 @default.
- W4200282368 cites W2955455227 @default.
- W4200282368 cites W2969670122 @default.
- W4200282368 cites W2981896826 @default.
- W4200282368 cites W3001039143 @default.
- W4200282368 cites W3006353096 @default.
- W4200282368 cites W3033261720 @default.