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- W4200307436 abstract "Developing low-cost, effective, and environmentally friendly heterogeneous catalysts for CO2 conversion into high-value-added products is a crucial task. In this study, Ferric ferrocyanide (Fe4[Fe(CN)6]3), the typical Prussian Blue (FeFe-PB) nanoparticles functionalized with hydroxide groups, is found to be the superior catalyst for CO2 and epoxide coupling to form cyclic carbonates with 100% selectivity and 99% yield under mild reaction conditions (1.0 MPa, 90 °C). A series of characterizations techniques showed that the FeFe-PB structure possesses excellent thermal and chemical stability and a high mesoporous surface area. The hydroxide group functionalized nanoparticles could preserve 97% of their initial activity after six reaction rounds. Additionally, we investigated the origin of epoxides activation with heterogeneous Lewis acid sites and surface hydroxide groups via hydrogen-bond interaction at the solid/liquid interface. These findings demonstrate a simple, ecologically safe, versatile, and efficient route for CO2 conversion into high-value chemicals by the FeFe-PB catalytic system." @default.
- W4200307436 created "2021-12-31" @default.
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- W4200307436 date "2022-03-01" @default.
- W4200307436 modified "2023-10-13" @default.
- W4200307436 title "Mesoporous Prussian Blue as the highly effective and selective catalyst for CO2 conversion into cyclic carbonates under mild conditions" @default.
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- W4200307436 doi "https://doi.org/10.1016/j.poly.2021.115640" @default.
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