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- W4200312814 abstract "The solubility of PMN in 13 organic solvents (methanol, ethanol, n-propanol, isopropanol, n-butanol, sec-butanol, isobutanol, acetone, acetonitrile, methyl acetate, ethyl acetate, n-propyl acetate, and isopropyl acetate) was determined by the gravimetric method over the temperatures ranging from 278.15 to 318.15 K at 0.1 MPa. The solubility of all selected solvents increases with increasing temperature; however, the change in methanol is substantially more than that in other solvents. Four models, including the modified Apelblat equation, the λh equation, the NRTL, and the van’t Hoff equation, were applied to correlate the experimental solubility data, which showed that a relative deviation is less than 3% with the four models. In addition, a KAT-LSER model was employed to quantitatively evaluate and describe the solvent effect, which indicate that the hydrogen bonding basicity of solvents has a greater effect on the solubility of PMN." @default.
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- W4200312814 date "2021-12-30" @default.
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- W4200312814 title "Solubility Measurement and Data Correlation of Pyrimethamine in 13 Pure Solvents at Temperatures from 278.15 to 318.15 K" @default.
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- W4200312814 doi "https://doi.org/10.1021/acs.jced.1c00672" @default.
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