Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200313011> ?p ?o ?g. }
- W4200313011 abstract "The gram-scale selective oxidation of biomass-based chemicals, in particular 5-hydroxymethylfurfural (HMF), into value-added 2,5-diformylfuran (DFF) has a high application potential but suffers from high cost, low selectivity, and harsh reaction conditions. Besides, the electrooxidation strategy requires the usage of expensive electrodes and struggles with low selectivity and efficiency, which restricts its further scaled-up application. In this regard, a continuous-flow system was developed through redox mediator I- /I2 for the efficient synthesis of DFF, which could accelerate the mass transfer of I- (I2 ) to aqueous (organic) phase and avoid over-oxidation to achieve high selectivity. After the solvent system, iodine concentration, and reaction time were optimized, highly efficient DFF synthesis (selectivity >99 %) could be achieved in the electrochemical flow system using inexpensive graphite felt (GF) as electrode. Moreover, selective HMF oxidation was paired with the hydrogen evolution reaction with increased efficiency after using in-situ-loaded GF-CoS2 /CoS and GF-Pt electrodes. As a result, the required energy to achieve the gram-scale synthesis of DFF was significantly reduced, demonstrating outstanding potential for large-scale production of the target product." @default.
- W4200313011 created "2021-12-31" @default.
- W4200313011 creator A5015813850 @default.
- W4200313011 creator A5019691378 @default.
- W4200313011 creator A5049401066 @default.
- W4200313011 creator A5056863791 @default.
- W4200313011 creator A5065482772 @default.
- W4200313011 creator A5076784728 @default.
- W4200313011 creator A5077352796 @default.
- W4200313011 creator A5079020384 @default.
- W4200313011 creator A5085766817 @default.
- W4200313011 date "2022-01-18" @default.
- W4200313011 modified "2023-10-14" @default.
- W4200313011 title "Selective Electrosynthesis of 2,5‐Diformylfuran in a Continuous‐Flow System" @default.
- W4200313011 cites W1983683645 @default.
- W4200313011 cites W2031892601 @default.
- W4200313011 cites W2062596783 @default.
- W4200313011 cites W2070497422 @default.
- W4200313011 cites W2073741113 @default.
- W4200313011 cites W2108961784 @default.
- W4200313011 cites W2128417005 @default.
- W4200313011 cites W2148298201 @default.
- W4200313011 cites W2165682602 @default.
- W4200313011 cites W2322093632 @default.
- W4200313011 cites W2322896908 @default.
- W4200313011 cites W2481885882 @default.
- W4200313011 cites W2521028017 @default.
- W4200313011 cites W2522671493 @default.
- W4200313011 cites W2595027778 @default.
- W4200313011 cites W2608225267 @default.
- W4200313011 cites W2755382413 @default.
- W4200313011 cites W2773056917 @default.
- W4200313011 cites W2790604732 @default.
- W4200313011 cites W2792132123 @default.
- W4200313011 cites W2793365652 @default.
- W4200313011 cites W2801305065 @default.
- W4200313011 cites W2808016672 @default.
- W4200313011 cites W2868762894 @default.
- W4200313011 cites W2887691089 @default.
- W4200313011 cites W2898246313 @default.
- W4200313011 cites W2913824278 @default.
- W4200313011 cites W2949384000 @default.
- W4200313011 cites W2950047581 @default.
- W4200313011 cites W2951065038 @default.
- W4200313011 cites W2965255951 @default.
- W4200313011 cites W2970759029 @default.
- W4200313011 cites W2972788178 @default.
- W4200313011 cites W2981645161 @default.
- W4200313011 cites W3006404697 @default.
- W4200313011 cites W3010951050 @default.
- W4200313011 cites W3019050035 @default.
- W4200313011 cites W3036054647 @default.
- W4200313011 cites W3037063247 @default.
- W4200313011 cites W3092036991 @default.
- W4200313011 cites W3092832375 @default.
- W4200313011 cites W3162429781 @default.
- W4200313011 cites W4230685241 @default.
- W4200313011 doi "https://doi.org/10.1002/cssc.202102596" @default.
- W4200313011 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34927792" @default.
- W4200313011 hasPublicationYear "2022" @default.
- W4200313011 type Work @default.
- W4200313011 citedByCount "4" @default.
- W4200313011 countsByYear W42003130112022 @default.
- W4200313011 countsByYear W42003130112023 @default.
- W4200313011 crossrefType "journal-article" @default.
- W4200313011 hasAuthorship W4200313011A5015813850 @default.
- W4200313011 hasAuthorship W4200313011A5019691378 @default.
- W4200313011 hasAuthorship W4200313011A5049401066 @default.
- W4200313011 hasAuthorship W4200313011A5056863791 @default.
- W4200313011 hasAuthorship W4200313011A5065482772 @default.
- W4200313011 hasAuthorship W4200313011A5076784728 @default.
- W4200313011 hasAuthorship W4200313011A5077352796 @default.
- W4200313011 hasAuthorship W4200313011A5079020384 @default.
- W4200313011 hasAuthorship W4200313011A5085766817 @default.
- W4200313011 hasConcept C118792377 @default.
- W4200313011 hasConcept C127413603 @default.
- W4200313011 hasConcept C132482357 @default.
- W4200313011 hasConcept C147789679 @default.
- W4200313011 hasConcept C161790260 @default.
- W4200313011 hasConcept C17525397 @default.
- W4200313011 hasConcept C178790620 @default.
- W4200313011 hasConcept C179104552 @default.
- W4200313011 hasConcept C184651966 @default.
- W4200313011 hasConcept C185592680 @default.
- W4200313011 hasConcept C193115255 @default.
- W4200313011 hasConcept C21951064 @default.
- W4200313011 hasConcept C2780471494 @default.
- W4200313011 hasConcept C42360764 @default.
- W4200313011 hasConcept C52859227 @default.
- W4200313011 hasConcept C55904794 @default.
- W4200313011 hasConceptScore W4200313011C118792377 @default.
- W4200313011 hasConceptScore W4200313011C127413603 @default.
- W4200313011 hasConceptScore W4200313011C132482357 @default.
- W4200313011 hasConceptScore W4200313011C147789679 @default.
- W4200313011 hasConceptScore W4200313011C161790260 @default.
- W4200313011 hasConceptScore W4200313011C17525397 @default.
- W4200313011 hasConceptScore W4200313011C178790620 @default.
- W4200313011 hasConceptScore W4200313011C179104552 @default.
- W4200313011 hasConceptScore W4200313011C184651966 @default.
- W4200313011 hasConceptScore W4200313011C185592680 @default.