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- W4200314931 abstract "Abstract The discovery of new polymer functions is intrinsically tied to the synthesis of diverse structures. Herein we report the synthesis of a new polymer library precursor, poly[N‐(12‐carboxyl‐3,6,9‐trioxado) methacrylamide] (pCTMAAm), that is functionalizable with hydrophilic or hydrophobic ligands in both protic and aprotic solvents. The polymer is made through RAFT polymerization with narrow dispersities. Carboxylic acid groups terminate the pCTMAAm side chains, which allows conjugation of both hydrophobic and hydrophilic groups. As a demonstration, three very different ligands, agmantine (cation), galactosamine (polyol) and hexylamine (hydrophobic), were conjugated to pCTMAAm using DMTTM as a condensing agent with greater than 80% conjugation efficiency. To demonstrate the potential utility of the amphiphilic polymer, a polymer library containing side chains with a series of alkanes and varying degrees of substitution was synthesized showing lower critical solution temperature (LCST) profiles that span a temperature range of 7 °C to above 90 °C in water. Multivariate linear regression analysis of the polymer library was used to understand how polymer composition correlates to LCST, using molecular weight, alkane length and degree of substitution as continuous variables. The outcome showed that alkane length has the greatest influence on LCST and that LCST can be estimated using these material composition inputs." @default.
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- W4200314931 date "2021-12-26" @default.
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- W4200314931 title "An amphiphilic polymer for the synthesis of diverse polymer libraries exemplified using conjugates with lower critical solution temperatures that span water's liquid state" @default.
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- W4200314931 doi "https://doi.org/10.1002/pol.20200890" @default.
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