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- W4200316489 abstract "Single-crystal cathode with a submicron particle size exhibits better cyclic stability and safety than their polycrystalline counterparts. However, high-temperature sintering, tedious steps, and unexpected product greatly hinder its industrial applications. Herein, we proposed to prepare single-crystal LiNi0.7Co0.15Mn0.15O2 by a sol–gel method, which can achieve uniform mixing at the molecular level. Besides, particle agglomeration almost does not occur for the products obtained at 890 °C, so the synthesis route does not require any crushing or molten-salt addition process. Single-crystal cathode particles have a diameter of about 1 μm. Compared with the conventional polycrystalline LiNi0.7Co0.15Mn0.15O2, the as-prepared single-crystal material exhibits improved thermal stability, less microcrack, and lower transition-metal dissolution. As a result, the long-life performance is improved for both coin cells and Al-shell cells." @default.
- W4200316489 created "2021-12-31" @default.
- W4200316489 creator A5000432967 @default.
- W4200316489 creator A5000713238 @default.
- W4200316489 date "2021-12-17" @default.
- W4200316489 modified "2023-10-16" @default.
- W4200316489 title "Synthesis of Single-Crystal LiNi<sub>0.7</sub>Co<sub>0.15</sub>Mn<sub>0.15</sub>O<sub>2</sub> Materials for Li-Ion Batteries by a Sol–Gel Method" @default.
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- W4200316489 doi "https://doi.org/10.1021/acsaem.1c02939" @default.
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