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- W4200329063 abstract "Syndioselective polymerization of unprotected polar styrenes has achieved great success via specially designed catalysts and the establishment of self-assisted theory. In contrast, isospecific polymerization of polar styrenes has remained less explored. Herein, we present new racemic ansa-bis(benz[e]indenyl) rare-earth metal complexes and their high activity and perfect isoselectivity (mmmm>99 %) for the polymerization of unmasked polar styrenes without any activators. Moreover, the copolymerizations of para- and meta-methoxystyrenes with styrene give gradient and random copolymers, respectively. The insertion rate of polar monomers could be readily tuned in the range of 0-100 mol % by changing their loading ratios. The resultant isotactic polar polystyrenes are quantitatively transformed into hydroxyl or methylsulfonyl polystyrenes with high Tg s. DFT calculations reveal the isospecific mechanism." @default.
- W4200329063 created "2021-12-31" @default.
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- W4200329063 date "2022-01-11" @default.
- W4200329063 modified "2023-10-14" @default.
- W4200329063 title "Isospecific (Co)polymerization of Unmasked Polar Styrenes by Neutral Rare‐Earth Metal Catalysts" @default.
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- W4200329063 doi "https://doi.org/10.1002/anie.202112966" @default.
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