Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200330655> ?p ?o ?g. }
- W4200330655 endingPage "541" @default.
- W4200330655 startingPage "533" @default.
- W4200330655 abstract "Three new antimonide Zintl phases, RbGaSb2, CsGaSb2, and CsInSb2, were discovered during exploration of corresponding A-M-Sb (A = Rb, Cs; M = Ga, In) ternary systems while searching for new clathrates. The AGaSb2 phases crystallize in the tetragonal space group P42/nmc (No. 137) in the LiBS2 structure type, while CsInSb2 crystallizes in lower symmetry in the orthorhombic space group Cmce (No. 64) in the KGaSb2 structure type with additional disorder of one of the Cs sites. The crystal structures of all three reported AMSb2 compounds are composed of two-dimensional [MSb2]- tetrahedral layers separated by Rb+ or Cs+ cations. [MSb2]- layers are built from fused M-Sb pentagons and hexagons, which are also the main structural units for A8M27Sb19 clathrate cages. The semiconductor nature of AMSb2 was suggested by band structure calculations and confirmed by transport property characterization. CsGaSb2 is a rare example of an n-type pnictide Zintl phase. All reported compounds exhibit low thermal conductivity typical for complex antimonides of heavy elements." @default.
- W4200330655 created "2021-12-31" @default.
- W4200330655 creator A5053000794 @default.
- W4200330655 creator A5076891744 @default.
- W4200330655 creator A5088315253 @default.
- W4200330655 date "2021-12-14" @default.
- W4200330655 modified "2023-09-25" @default.
- W4200330655 title "From Three-Dimensional Clathrates to Two-Dimensional Zintl Phases AMSb<sub>2</sub> (A = Rb, Cs; M = Ga, In) Composed of Pentagonal M–Sb Rings" @default.
- W4200330655 cites W1960920554 @default.
- W4200330655 cites W1968568721 @default.
- W4200330655 cites W1970966618 @default.
- W4200330655 cites W1972574548 @default.
- W4200330655 cites W1978704057 @default.
- W4200330655 cites W1979118016 @default.
- W4200330655 cites W1981925137 @default.
- W4200330655 cites W1992152443 @default.
- W4200330655 cites W1993408164 @default.
- W4200330655 cites W1997702975 @default.
- W4200330655 cites W2000857547 @default.
- W4200330655 cites W2001061882 @default.
- W4200330655 cites W2003113305 @default.
- W4200330655 cites W2009583693 @default.
- W4200330655 cites W2009867601 @default.
- W4200330655 cites W2014394054 @default.
- W4200330655 cites W2038097554 @default.
- W4200330655 cites W2039557183 @default.
- W4200330655 cites W2047480296 @default.
- W4200330655 cites W2049301745 @default.
- W4200330655 cites W2051805196 @default.
- W4200330655 cites W2066958450 @default.
- W4200330655 cites W2071265202 @default.
- W4200330655 cites W2079287410 @default.
- W4200330655 cites W2079980767 @default.
- W4200330655 cites W2082400705 @default.
- W4200330655 cites W2083094416 @default.
- W4200330655 cites W2089681190 @default.
- W4200330655 cites W2102141179 @default.
- W4200330655 cites W2110875966 @default.
- W4200330655 cites W2122812469 @default.
- W4200330655 cites W2131350133 @default.
- W4200330655 cites W2159147401 @default.
- W4200330655 cites W2162121092 @default.
- W4200330655 cites W2167233005 @default.
- W4200330655 cites W2317457588 @default.
- W4200330655 cites W2319166545 @default.
- W4200330655 cites W2332661160 @default.
- W4200330655 cites W2334231876 @default.
- W4200330655 cites W2339714630 @default.
- W4200330655 cites W2528736790 @default.
- W4200330655 cites W2573977381 @default.
- W4200330655 cites W2601255770 @default.
- W4200330655 cites W2613657644 @default.
- W4200330655 cites W2777376843 @default.
- W4200330655 cites W2782698368 @default.
- W4200330655 cites W2788941938 @default.
- W4200330655 cites W2811047282 @default.
- W4200330655 cites W2889685884 @default.
- W4200330655 cites W2949425368 @default.
- W4200330655 cites W2951186662 @default.
- W4200330655 cites W2974083793 @default.
- W4200330655 cites W2981770803 @default.
- W4200330655 cites W2997016422 @default.
- W4200330655 cites W3005899603 @default.
- W4200330655 cites W3007792729 @default.
- W4200330655 cites W3083957559 @default.
- W4200330655 cites W3085567128 @default.
- W4200330655 cites W3087432803 @default.
- W4200330655 cites W3171654811 @default.
- W4200330655 cites W3193517667 @default.
- W4200330655 cites W3209395000 @default.
- W4200330655 cites W4211190141 @default.
- W4200330655 cites W4236807592 @default.
- W4200330655 cites W85709498 @default.
- W4200330655 doi "https://doi.org/10.1021/acs.inorgchem.1c03217" @default.
- W4200330655 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/34905342" @default.
- W4200330655 hasPublicationYear "2021" @default.
- W4200330655 type Work @default.
- W4200330655 citedByCount "1" @default.
- W4200330655 countsByYear W42003306552023 @default.
- W4200330655 crossrefType "journal-article" @default.
- W4200330655 hasAuthorship W4200330655A5053000794 @default.
- W4200330655 hasAuthorship W4200330655A5076891744 @default.
- W4200330655 hasAuthorship W4200330655A5088315253 @default.
- W4200330655 hasConcept C100402318 @default.
- W4200330655 hasConcept C115624301 @default.
- W4200330655 hasConcept C121332964 @default.
- W4200330655 hasConcept C170751736 @default.
- W4200330655 hasConcept C178790620 @default.
- W4200330655 hasConcept C185592680 @default.
- W4200330655 hasConcept C192095803 @default.
- W4200330655 hasConcept C199360897 @default.
- W4200330655 hasConcept C26873012 @default.
- W4200330655 hasConcept C2776845273 @default.
- W4200330655 hasConcept C2778133893 @default.
- W4200330655 hasConcept C2781060337 @default.
- W4200330655 hasConcept C37243968 @default.
- W4200330655 hasConcept C41008148 @default.
- W4200330655 hasConcept C54101563 @default.