Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200340322> ?p ?o ?g. }
- W4200340322 abstract "Abstract Cu 2 O microparticles with controllable crystal planes and relatively high stability have been recognized as a good platform to understand the mechanism of the electrocatalytic CO 2 reduction reaction (CO 2 RR). Herein, we demonstrate that the in situ generated Cu 2 O/Cu interface plays a key role in determining the selectivity of methane formation, rather than the initial crystal plane of the reconstructed Cu 2 O microparticles. Experimental results indicate that the methane evolution is dominated on all three different crystal planes with similar Tafel slopes and long‐term stabilities. Density functional theory (DFT) calculations further reveal that *CO is protonated via a similar bridge configuration at the Cu 2 O/Cu interface, regardless of the initial crystal planes of Cu 2 O. The Gibbs free energy changes (Δ G ) of *CHO on different reconstructed Cu 2 O planes are close and more negative than that of *OCCOH, indicating the methane formation is more favorable than ethylene on all Cu 2 O crystal planes." @default.
- W4200340322 created "2021-12-31" @default.
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- W4200340322 date "2021-12-27" @default.
- W4200340322 modified "2023-10-15" @default.
- W4200340322 title "Crystal plane is not the key factor for CO2‐to‐methane electrosynthesis on reconstructed Cu2O microparticles" @default.
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- W4200340322 doi "https://doi.org/10.1002/ange.202114080" @default.
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