Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200375648> ?p ?o ?g. }
- W4200375648 abstract "Abstract Imidazolium salts have ubiquitous applications in energy research, catalysis, materials and medicinal sciences. Here, we report a new strategy for the synthesis of diverse heteroatom‐functionalized imidazolium and imidazolinium salts from easily available 1,4‐diaza‐1,3‐butadienes in one step. The strategy relies on a discovered family of unprecedented nucleophilic addition/cyclization reactions with trialkyl orthoformates and heteroatomic nucleophiles. To probe general areas of application, synthesized N‐heterocyclic carbene (NHC) precursors were feasible for direct metallation to give functionalized M/carbene complexes (M=Pd, Ni, Cu, Ag, Au), which were isolated in individual form. The utility of the chloromethyl function for the postmodification of the synthesized salts and Pd/carbene complexes was demonstrated. The obtained complexes and imidazolium salts demonstrated good activities in Pd‐ or Ni‐catalyzed model cross‐coupling and C−H activation reactions." @default.
- W4200375648 created "2021-12-31" @default.
- W4200375648 creator A5029774717 @default.
- W4200375648 creator A5030204094 @default.
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- W4200375648 creator A5080511511 @default.
- W4200375648 creator A5084744210 @default.
- W4200375648 date "2022-01-24" @default.
- W4200375648 modified "2023-10-16" @default.
- W4200375648 title "One‐Step Access to Heteroatom‐Functionalized Imidazol(in)ium Salts" @default.
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