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• W4200380441 abstract "Gold nanomaterials have widespread applications across multiple areas of science and technology. Sulfur-containing ligands (thiols and thioethers) have been traditionally used as ligands to protect and functionalize these materials. N-Heterocyclic carbenes (NHCs) have recently emerged as organic alternatives to thiols in stabilizing gold nanoparticles (AuNPs) and flat surfaces. In fact, gold-containing materials decorated with NHCs have been shown to withstand a variety of harsh conditions. However, such materials still suffer from limited stability in the presence of thiols, such as the biologically relevant glutathione, in aqueous media. Here, we report the synthesis and application of polymeric mesoionic NHC–Au(I) complexes as precursors to polyNHC-stabilized AuNPs. Using copper-catalyzed alkyne–azide cycloaddition polymerization of diazide- and dialkyne-containing monomers, we directly install 1,2,3-triazole groups, as precursors to mesoionic carbenes, on the backbone of the resulting polymers. This effectively eliminates the need to presynthesize NHC–Au(I)-containing monomers to access this class of polymers. Using these polymers as the substrate, the resulting robust AuNPs, protected by a catenated network of NHCs, demonstrate exceptional stabilities in aqueous media under various conditions, particularly against high concentrations of glutathione (up to 6 mM) for extended periods of time (up to 10 days). Moreover, the use of the macromolecular substrate, compared to small NHC–Au complexes used thus far yielding relatively small AuNPs (∼5 nm), results in the formation of larger AuNPs (∼12 nm). Such enhanced stabilities in aqueous media together with their larger diameters make these materials promising for potential applications in nanomedicine. To highlight their multifunctionality, we also demonstrate their catalytic activity in the reduction of 4-nitrophenol." @default.
• W4200380441 created "2021-12-31" @default.
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• W4200380441 date "2021-12-14" @default.
• W4200380441 modified "2023-10-03" @default.
• W4200380441 title "Robust Water-Soluble Gold Nanoparticles via Polymerized Mesoionic <i>N</i>-Heterocyclic Carbene–Gold(I) Complexes" @default.
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• W4200380441 doi "https://doi.org/10.1021/acs.chemmater.1c02899" @default.
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