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- W4200384015 abstract "A novel MoSi2–Al2O3 composite coating was prepared on Mo-based TZM alloy by slurry sintering method. The oxidation behavior of the coating was evaluated at 1600 °C in static air. Microstructure and phase composition of the as-prepared and oxidized coatings were characterized, and the antioxidant mechanism of the coating at high temperature was discussed. A three-layer structure was observed in the as-prepared coating, consisting of a ∼2 μm thick Mo5Si3 diffusion layer, a ∼65 μm thick MoSi2 inner layer and a ∼36 μm thick outer layer of mixture of MoSi2 and Al2O3. After oxidation at 1600 °C for 5 h, all MoSi2 phases were completely converted to intermediate silicide Mo5Si3 by solid-state diffusion, and the formed Mo5Si3 phase would be transformed into Mo3Si phase with further extending the oxidation time. Furthermore, a dense oxide layer of SiO2-mullite was formed on the specimen surface, which can effectively protect the material to further oxidation. The MoSi2–Al2O3 coating could protect the substrate effectively at 1600 °C for 20 h without failure. The enhanced oxidation resistance of MoSi2–Al2O3 coating is due to the formation of multi-layer structure containing a SiO2-mullite composite oxide outer layer with high thermal stability and low oxygen permeability." @default.
- W4200384015 created "2021-12-31" @default.
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- W4200384015 date "2022-04-01" @default.
- W4200384015 modified "2023-10-03" @default.
- W4200384015 title "High temperature oxidation behavior of MoSi2–Al2O3 composite coating on TZM alloy" @default.
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- W4200384015 doi "https://doi.org/10.1016/j.ceramint.2021.12.310" @default.
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