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- W4200402015 abstract "• Zn-Bi-O systems (spinel type) prepared by two different methods. • A mixed of oxides (ZnO/Bi 2 O 3 ) is obtained by hydrothermal method while Zn-Bi-O ternary oxide is obtained by sol–gel. • The leaching of Zn 2+ and Bi 3+ ions and their interaction with caffeic acid to form complexes have been studied. • Excellent visible activity for the removal of caffeic acid for both Zn-Bi-O systems. • By addition of AgNO 3 , dyes degradation considerably improved. Different Zn-Bi-O composites were synthesized following the starting chemical molar composition of ZnBi 2 O 4 spinels by a sol–gel method, (ZnBiO)-SG, and its subsequent hydrothermal treatment, (ZnBiO)-HT. The acquired X-ray diffractograms after sequential thermal treatments at a programmed rate indicate that both precursors evolved, after calcination at 500 °C, to materials (ZnBiO) with different stoichiometry. The use of different characterization techniques (both FT-IR and TEM), allowed us to establish that, with the sol–gel process a mixed ZnO/Bi 2 O 3 oxide is generated, while after hydrothermal process a ternary Zn-Bi-O oxide is formed, with small amounts of residual ZnO. The photocatalytic properties of the synthesized samples were evaluated using Caffeic acid, Rhodamine B and Methyl Orange as model substrates. It can be concluded that both catalysts showed excellent photocatalytic activity for the degradation of trans -caffeic acid under both UV and visible illumination. The leaching process (in particular of zinc), which is produced with the illumination time (in particular under UV illumination) in the presence of oxygen, raises the hypothesis of a foreseeable formation of complexes (photochemically stable or unstable) of caffeic acid with Zn 2+ and Bi 3+ ions. The plausible donor/acceptor interactions between the toxic molecules studied and the Zn 2+ and Bi 3+ ions, could condition the degradation processes, by means of a photoassisted process that would take place both, in the heterogeneous (photocatalytic) and homogeneous (photoassisted) phases. For the degradation processes of Rhodamine B and Methyl Orange, additional experimental conditions are studied that significantly improved their photocatalytic degradation." @default.
- W4200402015 created "2021-12-31" @default.
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- W4200402015 date "2022-04-01" @default.
- W4200402015 modified "2023-10-18" @default.
- W4200402015 title "Insights into the structural and physicochemical properties of Zn-Bi-O composites for efficient photodegradation of caffeic acid, rhodamine B and methyl orange" @default.
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- W4200402015 doi "https://doi.org/10.1016/j.apsusc.2021.152351" @default.
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