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- W4200414729 abstract "We show, using a model coupling mass transport and liquid theory calculations for a charge-stabilized colloidal dispersion, that diffusion significantly limits measurement times of its Equation Of State (EOS), osmotic pressure vs composition, using the osmotic compression technique. Following this result, we present a microfluidic chip allowing one to measure the entire EOS of a charged dispersion at the nanoliter scale in a few hours. We also show that time-resolved analyses of relaxation to equilibrium in this microfluidic experiment lead to direct estimates of the collective diffusion coefficient of the dispersion in Donnan equilibrium with a salt reservoir." @default.
- W4200414729 created "2021-12-31" @default.
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- W4200414729 date "2021-12-14" @default.
- W4200414729 modified "2023-10-17" @default.
- W4200414729 title "Microfluidic osmotic compression of a charge-stabilized colloidal dispersion: Equation of state and collective diffusion coefficient" @default.
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- W4200414729 doi "https://doi.org/10.1103/physreve.104.l062601" @default.
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