Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200424868> ?p ?o ?g. }
- W4200424868 endingPage "25505" @default.
- W4200424868 startingPage "25500" @default.
- W4200424868 abstract "Abstract Atomically dispersed metal‐nitrogen sites show great prospect for the oxygen reduction reaction (ORR), whereas the unsatisfactory adsorption‐desorption behaviors of oxygenated intermediates on the metal centers impede improvement of the ORR performance. We propose a new conceptual strategy of introducing sacrificial bonds to remold the local coordination of Fe−N x sites, via controlling the dynamic transformation of the Fe−S bonds in the Fe−N−C single‐atom catalyst. Spectroscopic and theoretical results reveal that the selective cleavage of the sacrificial Fe−S bonds induces the incorporation of the electron‐withdrawing oxidized sulfur on the Fe centers. The newly functionalized moieties endow the catalyst with superior ORR activity and remarkable stability, owing to the reduced electron localization around the Fe centers facilitating the desorption of ORR intermediates. These findings provide a unique perspective for precisely controlling the coordination structure of single‐atom materials to optimize their activity." @default.
- W4200424868 created "2021-12-31" @default.
- W4200424868 creator A5054659240 @default.
- W4200424868 creator A5064945531 @default.
- W4200424868 creator A5069574614 @default.
- W4200424868 date "2021-10-20" @default.
- W4200424868 modified "2023-10-17" @default.
- W4200424868 title "Dynamic Control of Sacrificial Bond Transformation in the Fe−N−C Single‐Atom Catalyst for Molecular Oxygen Reduction" @default.
- W4200424868 cites W2007963028 @default.
- W4200424868 cites W2012759651 @default.
- W4200424868 cites W2062460814 @default.
- W4200424868 cites W2111770307 @default.
- W4200424868 cites W2329247413 @default.
- W4200424868 cites W2330994498 @default.
- W4200424868 cites W2752177772 @default.
- W4200424868 cites W2805483123 @default.
- W4200424868 cites W2810052757 @default.
- W4200424868 cites W2888882000 @default.
- W4200424868 cites W2891500160 @default.
- W4200424868 cites W2920653331 @default.
- W4200424868 cites W2922425858 @default.
- W4200424868 cites W2923015936 @default.
- W4200424868 cites W2930621785 @default.
- W4200424868 cites W2937321819 @default.
- W4200424868 cites W2977270706 @default.
- W4200424868 cites W2979917947 @default.
- W4200424868 cites W2993510745 @default.
- W4200424868 cites W2998463740 @default.
- W4200424868 cites W3004072845 @default.
- W4200424868 cites W3009298691 @default.
- W4200424868 cites W3034967233 @default.
- W4200424868 cites W3066041726 @default.
- W4200424868 cites W3087043487 @default.
- W4200424868 cites W3103953151 @default.
- W4200424868 cites W3123025549 @default.
- W4200424868 cites W3130506134 @default.
- W4200424868 cites W3135856016 @default.
- W4200424868 cites W3136472111 @default.
- W4200424868 cites W3149882695 @default.
- W4200424868 cites W3158055689 @default.
- W4200424868 cites W3177227149 @default.
- W4200424868 cites W4205640227 @default.
- W4200424868 cites W4206141536 @default.
- W4200424868 cites W4206939493 @default.
- W4200424868 cites W4240956886 @default.
- W4200424868 cites W4250485040 @default.
- W4200424868 cites W4256645293 @default.
- W4200424868 doi "https://doi.org/10.1002/ange.202111761" @default.
- W4200424868 hasPublicationYear "2021" @default.
- W4200424868 type Work @default.
- W4200424868 citedByCount "7" @default.
- W4200424868 countsByYear W42004248682022 @default.
- W4200424868 countsByYear W42004248682023 @default.
- W4200424868 crossrefType "journal-article" @default.
- W4200424868 hasAuthorship W4200424868A5054659240 @default.
- W4200424868 hasAuthorship W4200424868A5064945531 @default.
- W4200424868 hasAuthorship W4200424868A5069574614 @default.
- W4200424868 hasConcept C147789679 @default.
- W4200424868 hasConcept C149635348 @default.
- W4200424868 hasConcept C150394285 @default.
- W4200424868 hasConcept C161790260 @default.
- W4200424868 hasConcept C162711632 @default.
- W4200424868 hasConcept C178790620 @default.
- W4200424868 hasConcept C179104552 @default.
- W4200424868 hasConcept C185592680 @default.
- W4200424868 hasConcept C21951064 @default.
- W4200424868 hasConcept C3044715 @default.
- W4200424868 hasConcept C41008148 @default.
- W4200424868 hasConcept C518881349 @default.
- W4200424868 hasConcept C540031477 @default.
- W4200424868 hasConcept C544153396 @default.
- W4200424868 hasConcept C58312451 @default.
- W4200424868 hasConcept C75473681 @default.
- W4200424868 hasConcept C8010536 @default.
- W4200424868 hasConceptScore W4200424868C147789679 @default.
- W4200424868 hasConceptScore W4200424868C149635348 @default.
- W4200424868 hasConceptScore W4200424868C150394285 @default.
- W4200424868 hasConceptScore W4200424868C161790260 @default.
- W4200424868 hasConceptScore W4200424868C162711632 @default.
- W4200424868 hasConceptScore W4200424868C178790620 @default.
- W4200424868 hasConceptScore W4200424868C179104552 @default.
- W4200424868 hasConceptScore W4200424868C185592680 @default.
- W4200424868 hasConceptScore W4200424868C21951064 @default.
- W4200424868 hasConceptScore W4200424868C3044715 @default.
- W4200424868 hasConceptScore W4200424868C41008148 @default.
- W4200424868 hasConceptScore W4200424868C518881349 @default.
- W4200424868 hasConceptScore W4200424868C540031477 @default.
- W4200424868 hasConceptScore W4200424868C544153396 @default.
- W4200424868 hasConceptScore W4200424868C58312451 @default.
- W4200424868 hasConceptScore W4200424868C75473681 @default.
- W4200424868 hasConceptScore W4200424868C8010536 @default.
- W4200424868 hasFunder F4320321001 @default.
- W4200424868 hasIssue "48" @default.
- W4200424868 hasLocation W42004248681 @default.
- W4200424868 hasOpenAccess W4200424868 @default.
- W4200424868 hasPrimaryLocation W42004248681 @default.
- W4200424868 hasRelatedWork W1787461325 @default.
- W4200424868 hasRelatedWork W1984689874 @default.