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• W4200426244 abstract "In this study, the double-layered Aurivillius phases CaBi 2 Ta 2 O 9 (CBT) and PbBi 2 Ta 2 O 9 (PBT) were prepared through a hydrothermal route with NaOH as a mineralizer. XRD analysis confirmed that the CBT and PBT compounds were successfully formed and adopted an orthorhombic crystal structure with an [Formula: see text]2 1 am symmetry. Le Bail refinements of XRD data indicated that the unit cell volume of CBT was smaller than PBT and is associated with the smaller ionic radius of [Formula: see text] compared to [Formula: see text]. The surface morphology of both samples, as determined using SEM, demonstrated plate-like grains with anisotropic grain growth. It was found that the different ionic radii of [Formula: see text]-site cations ([Formula: see text] and [Formula: see text] strongly affected the structural, optical and electrical properties of the Aurivillius phase. The occupation of smaller [Formula: see text] cations induced a higher structural distortion, which resulted in higher bandgap ([Formula: see text] energy and ferroelectric transition temperature ([Formula: see text] of CBT, compared to those of PBT." @default.
• W4200426244 created "2021-12-31" @default.
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• W4200426244 date "2021-12-15" @default.
• W4200426244 modified "2023-09-23" @default.
• W4200426244 title "Hydrothermal synthesis of ABi2Ta2<b>O</b>9Aurivillius phase: A comparative study of A-site cation size on structure, dielectric, optical properties" @default.
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• W4200426244 doi "https://doi.org/10.1142/s2010135x21500302" @default.
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