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- W4200430217 abstract "Despite rapid progress over the past decade, most polycondensation systems even upon a small structural variation of the building units eventually result in amorphous polymers other than the desired crystalline covalent organic frameworks. This synthetic dilemma is a central and challenging issue of the field. Here we report a novel approach based on module-patterned polymerization to enable efficient and designed synthesis of crystalline porous polymeric frameworks. This strategy features a wide applicability to allow the use of various knots of different structures, enables polycondensation with diverse linkers, and develops a diversity of novel crystalline 2D polymers and frameworks, as demonstrated by using the C=C bond-formation polycondensation reaction. The new sp2 -carbon frameworks are highly emissive and enable up-conversion luminescence, offer low band gap semiconductors with tunable band structures, and achieve ultrahigh charge mobilities close to theoretically predicted maxima." @default.
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- W4200430217 date "2022-01-11" @default.
- W4200430217 modified "2023-10-04" @default.
- W4200430217 title "Module‐Patterned Polymerization towards Crystalline 2D sp <sup>2</sup> ‐Carbon Covalent Organic Framework Semiconductors" @default.
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- W4200430217 doi "https://doi.org/10.1002/anie.202115020" @default.
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