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• W4200430965 abstract "Chiral gold(I) acetylide trinuclear complexes 1-3 based on the cyclotribenzylene platform and terminal PR3 ligands (R=Ph, Et, and Cy, respectively), were characterized and their light emission studied. They exhibited long-lived blue phosphorescence in CHCl3 and a weak fluorescence in the UV. In MeOH/CHCl3 mixtures of >1:1 volume ratio, 1 and 2 exhibited a new emission band at ca. 540 nm that developed at the expense of the UV emission. DLS studies demonstrated the presence of molecular aggregates of Ø 30-80 nm. The green emission observed in MeOH-rich solvent mixtures was therefore induced by aggregation, and could originate from Au⋅⋅⋅Au interactions. The AIE spectrum of 3 was observed only in solutions containing 99 % of MeOH, and correlated with its solid state emission. The AIE profiles of the enantiomers of 1 differed from that of rac-1, suggesting that the latter is a true racemate." @default.
• W4200430965 created "2021-12-31" @default.
• W4200430965 creator A5017947172 @default.
• W4200430965 creator A5030602183 @default.
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• W4200430965 creator A5081740709 @default.
• W4200430965 date "2021-12-27" @default.
• W4200430965 modified "2023-10-06" @default.
• W4200430965 title "Alkynylgold(I) <i>C</i> ₃ ‐Chiral Concave Complexes: Aggregation and Luminescence" @default.
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• W4200430965 doi "https://doi.org/10.1002/chem.202103759" @default.

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