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- W4200431520 abstract "Unnatural α-amino acids are important synthetic targets in the field of peptide science. Herein we report an efficient, versatile, and straightforward strategy for the synthesis of homophenylalanine derivatives via the nickel-catalyzed Csp3-Csp3 cross-coupling of (fluoro)benzyl bromides/chlorides with natural α-amino-acid-derived alkylzinc reagents. The current protocol features the advantages of a low-cost nickel catalyst system, synthetic convenience, and the tolerance of rich functionality and stereochemistry." @default.
- W4200431520 created "2021-12-31" @default.
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- W4200431520 date "2021-12-27" @default.
- W4200431520 modified "2023-10-09" @default.
- W4200431520 title "Nickel-Catalyzed Cross-Coupling of Amino-Acid-Derived Alkylzinc Reagents with Alkyl Bromides/Chlorides: Access to Diverse Unnatural Amino Acids" @default.
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- W4200431520 doi "https://doi.org/10.1021/acs.orglett.1c03884" @default.
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