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• W4200432962 startingPage "188" @default.
• W4200432962 abstract "Photo- and electrocatalytic technologies hold great promise for activating inert chemical bonds under mild conditions, but rationally selecting a more suitable method in between to maximize the performance remains an open issue, which requires a fundamental understanding of their different catalytic mechanisms. Herein, by first-principles calculations, we systematically compare the activation mechanisms for the C-H bond of the CH4 molecule on TiO2(110) under the photo- and electrocatalytic modes without or with water involved. It quantitatively reveals that the activation barrier of the C-H bond decreases dramatically with a surprising 74% scale by photoexcitation relative to that in thermocatalysis (1.12 eV), while the barrier varies with a maximum promotion of only 5% even under -1 V/Å external electric field (EEF). By detailed geometric/electronic analysis, the superior photocatalytic activity is traced to the highly oxidative lattice Obr•- radical excited by a photohole (h+), which motivates the homolytic C-H bond scission. However, under EEF from -1 V/Å to 1 V/Å, it gives a relatively mild charge polarization on the TiO2(110) surface region and thus a limited promotion for breaking the weakly polar C-H bond. By contrast, in the presence of water, we find that EEF can facilitate CH4 activation indirectly assisted by the surface radical-like OH* species from the oxidative water cleavage at high oxidative potential (>1.85 V vs SHE), which explains the high energy cost to drive electrocatalytic CH4 conversion in experiment. Alternatively, we demonstrate that more efficient CH4 activation could be also achieved at much lower oxidative potential when integrating the light irradiation. In such a circumstance, EEF can not only promote the h+ accumulation at the catalyst surface but also help H2O deprotonation to form hydroxide, which can serve as an efficient hole-trapper to generate OH• radical (OH- + h+ → OH•), unveiling an interesting synergistic photoelectrocatalytic effect. This work could provide a fundamental insight into the different characteristics of photo- and electrocatalysis in modulating chemical bond cleavage." @default.
• W4200432962 created "2021-12-31" @default.
• W4200432962 creator A5043069455 @default.
• W4200432962 creator A5067222247 @default.
• W4200432962 date "2021-12-22" @default.
• W4200432962 modified "2023-10-13" @default.
• W4200432962 title "Optimally Selecting Photo- and Electrocatalysis to Facilitate CH₄ Activation on TiO₂(110) Surface: Localized Photoexcitation versus Global Electric-Field Polarization" @default.
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• W4200432962 doi "https://doi.org/10.1021/jacsau.1c00466" @default.
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