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• W4200437717 abstract "The [VO(His)2]HSO4.H2O complex designated as [VO(His)2] complex was prepared via reaction of histidine (His) with VOSO4. The most stable binding models of histidine in [VO(His)2] complex was calculated with density functional theory (DFT). The [VO(His)2]complex was subsequently immobilized within UiO-66-NH2, and designated as [VO(His)2][email protected]2. The prepared [VO(His)2][email protected]2 was characterized by means of FTIR, XRD, NMR, MS, EDX, TGA, BET and XPS techniques. The prepared complex compound was used as catalyst for epoxidation of some allyl alcohols. The high catalytic activity of [VO(His)2][email protected]2 in the epoxidation of geraniol with 94% conversion, 100% selectivity and TOF of 1093 h−1 is promising." @default.
• W4200437717 created "2021-12-31" @default.
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• W4200437717 date "2022-04-01" @default.
• W4200437717 modified "2023-09-25" @default.
• W4200437717 title "Synthesis and DFT study of binding models of histidine in [VO(His)2]complex and immobilization on UiO-66-NH2 as epoxidation catalyst of allyl alcohols" @default.
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• W4200437717 doi "https://doi.org/10.1016/j.molstruc.2021.132248" @default.
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