Matches in SemOpenAlex for { <https://semopenalex.org/work/W4200460298> ?p ?o ?g. }
- W4200460298 endingPage "24519" @default.
- W4200460298 startingPage "24514" @default.
- W4200460298 abstract "Abstract Biomimetic metal‐organic frameworks have attracted great attention as they can be used as bio‐inspired models, allowing us to gain important insights into how large biological molecules function as catalysts. In this work, we report the synthesis and utilization of such a metal‐metalloporphyrin framework (MMPF) that is constructed from a custom‐designed ligand as an efficient halogen bond donor catalyst for Diels–Alder reactions under ambient conditions. The implementation of fabricated halogen bonding capsule as binding pocket with high‐density C−Br bonds enabled the use of halogen bonding to facilitate organic transformations in their three‐dimensional cavities. Through combined experimental and computational studies, we showed that the substrate molecules diffuse through the pores of the MMPF, establishing a host‐guest system via the C−Br⋅⋅⋅π interaction. The formation of halogen bonds is a plausible explanation for the observed boosted catalytic efficiency in Diels–Alder reactions. Moreover, the unique capability of MMPF highlights new opportunities in using artificial non‐covalent binding pockets as highly tunable and selective catalytic materials." @default.
- W4200460298 created "2021-12-31" @default.
- W4200460298 creator A5031867459 @default.
- W4200460298 creator A5032832663 @default.
- W4200460298 creator A5034242852 @default.
- W4200460298 creator A5045372922 @default.
- W4200460298 creator A5067111953 @default.
- W4200460298 creator A5072912711 @default.
- W4200460298 creator A5075013971 @default.
- W4200460298 creator A5088222785 @default.
- W4200460298 date "2021-10-01" @default.
- W4200460298 modified "2023-09-27" @default.
- W4200460298 title "Functional Porphyrinic Metal–Organic Framework as a New Class of Heterogeneous Halogen‐Bond‐Donor Catalyst" @default.
- W4200460298 cites W1895486477 @default.
- W4200460298 cites W1963742978 @default.
- W4200460298 cites W1967812076 @default.
- W4200460298 cites W1969323559 @default.
- W4200460298 cites W1970386798 @default.
- W4200460298 cites W1972646318 @default.
- W4200460298 cites W1988752229 @default.
- W4200460298 cites W1997813480 @default.
- W4200460298 cites W1998430793 @default.
- W4200460298 cites W2018421937 @default.
- W4200460298 cites W2028257320 @default.
- W4200460298 cites W2030481799 @default.
- W4200460298 cites W2044106231 @default.
- W4200460298 cites W2047019847 @default.
- W4200460298 cites W2058518164 @default.
- W4200460298 cites W2059107251 @default.
- W4200460298 cites W2063496385 @default.
- W4200460298 cites W2064093334 @default.
- W4200460298 cites W2083351203 @default.
- W4200460298 cites W2089277691 @default.
- W4200460298 cites W2105333668 @default.
- W4200460298 cites W2106475364 @default.
- W4200460298 cites W2109135544 @default.
- W4200460298 cites W2122508191 @default.
- W4200460298 cites W2125635268 @default.
- W4200460298 cites W2134149462 @default.
- W4200460298 cites W2155579681 @default.
- W4200460298 cites W2159356452 @default.
- W4200460298 cites W2160294964 @default.
- W4200460298 cites W2168080697 @default.
- W4200460298 cites W2170402416 @default.
- W4200460298 cites W2265596863 @default.
- W4200460298 cites W2283564633 @default.
- W4200460298 cites W2298884395 @default.
- W4200460298 cites W2324633527 @default.
- W4200460298 cites W2326201467 @default.
- W4200460298 cites W2330856899 @default.
- W4200460298 cites W2346466964 @default.
- W4200460298 cites W2414809868 @default.
- W4200460298 cites W2442186283 @default.
- W4200460298 cites W2552570031 @default.
- W4200460298 cites W2588879951 @default.
- W4200460298 cites W2599634799 @default.
- W4200460298 cites W2609455338 @default.
- W4200460298 cites W2752027333 @default.
- W4200460298 cites W2765244540 @default.
- W4200460298 cites W2791594724 @default.
- W4200460298 cites W2889575089 @default.
- W4200460298 cites W2905765615 @default.
- W4200460298 cites W2945017930 @default.
- W4200460298 cites W2969803427 @default.
- W4200460298 cites W2981210402 @default.
- W4200460298 cites W3005163199 @default.
- W4200460298 cites W3016818751 @default.
- W4200460298 cites W3020583590 @default.
- W4200460298 cites W3036059291 @default.
- W4200460298 cites W3040766709 @default.
- W4200460298 cites W3047645376 @default.
- W4200460298 cites W3048454067 @default.
- W4200460298 cites W3158679856 @default.
- W4200460298 cites W3164241814 @default.
- W4200460298 cites W4230835859 @default.
- W4200460298 cites W4242401348 @default.
- W4200460298 cites W4243209490 @default.
- W4200460298 cites W4249978070 @default.
- W4200460298 cites W4252762169 @default.
- W4200460298 doi "https://doi.org/10.1002/ange.202111893" @default.
- W4200460298 hasPublicationYear "2021" @default.
- W4200460298 type Work @default.
- W4200460298 citedByCount "2" @default.
- W4200460298 countsByYear W42004602982023 @default.
- W4200460298 crossrefType "journal-article" @default.
- W4200460298 hasAuthorship W4200460298A5031867459 @default.
- W4200460298 hasAuthorship W4200460298A5032832663 @default.
- W4200460298 hasAuthorship W4200460298A5034242852 @default.
- W4200460298 hasAuthorship W4200460298A5045372922 @default.
- W4200460298 hasAuthorship W4200460298A5067111953 @default.
- W4200460298 hasAuthorship W4200460298A5072912711 @default.
- W4200460298 hasAuthorship W4200460298A5075013971 @default.
- W4200460298 hasAuthorship W4200460298A5088222785 @default.
- W4200460298 hasConcept C111368507 @default.
- W4200460298 hasConcept C112887158 @default.
- W4200460298 hasConcept C116569031 @default.
- W4200460298 hasConcept C127313418 @default.
- W4200460298 hasConcept C137277065 @default.