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- W4200476736 abstract "A rhodium(II)-catalyzed asymmetric cyclooligomerization of bifunctional monomers possessing triazolyl and vinyl groups at 2,3- and 3,4-positions on the thiophene ring is studied. Structurally interesting cyclic dimers in which thienylene and cyclopropylene units are alternately connected are obtained as the major components. The eight-membered rings in the center are non-planar and adopt a tub-shaped conformation. We also observe the phenomenon of racemization caused by a tub-to-tub ring-flipping, the activation energy of which is determined as 108 kJ mol-1 by electronic circular dichroism spectra measurement." @default.
- W4200476736 created "2021-12-31" @default.
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- W4200476736 date "2022-01-19" @default.
- W4200476736 modified "2023-10-16" @default.
- W4200476736 title "Synthesis, Structure, and Dynamics of Chiral Eight‐Membered Cyclic Molecules with Thienylene and Cyclopropylene Units Alternately Connected" @default.
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- W4200476736 doi "https://doi.org/10.1002/chem.202103962" @default.
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