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- W4200506712 abstract "A palladium-catalyzed N-H/B-H double activation of 1,2-dihydro-1,2-benzazaborines proceeded via cycloaddition with vinyl ethylene carbonate to produce polycyclic oxazaborolidines in 31-96 % yield. The key step in this process is the release of molecular hydrogen from a borate intermediate. Using a SPINOL-derived phosphoramidite as a chiral ligand, chiral oxazaborolidines were synthesized in good to high yields with excellent enantioselectivity (up to 95 % ee). The vinyl group of the resulting oxazaborolidine underwent metathesis, Heck reaction, and Wacker oxidation without affecting the oxazaborolidine framework." @default.
- W4200506712 created "2021-12-31" @default.
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- W4200506712 date "2021-12-29" @default.
- W4200506712 modified "2023-10-13" @default.
- W4200506712 title "Enantioselective Synthesis of Oxazaborolidines by Palladium‐Catalyzed N−H/B−H Double Activation of 1,2‐Azaborines" @default.
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- W4200506712 doi "https://doi.org/10.1002/anie.202113558" @default.
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