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- W4200508889 abstract "We have developed a high-efficiency and practical Cu-catalyzed cross-coupling to directly construct versatile α-aryl-esters by utilizing readily available aryl bromides (or chlorides) and malonates. These gram-scale approaches occur with turnovers of up to 1560 and are smoothly conducted by the usage of a low catalyst loading, a new available ligand, and a green solvent. A variety of functional groups are tolerated, and the application occurs with α-aryl-esters to access nonsteroidal anti-inflammatory drugs (NSAIDs) on the gram scale." @default.
- W4200508889 created "2021-12-31" @default.
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- W4200508889 date "2021-12-21" @default.
- W4200508889 modified "2023-10-14" @default.
- W4200508889 title "Copper-Catalyzed Ullmann-Type Coupling and Decarboxylation Cascade of Arylhalides with Malonates to Access α-Aryl Esters" @default.
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- W4200508889 doi "https://doi.org/10.1021/acs.orglett.1c03688" @default.
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