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- W4200518085 abstract "In the presented work on chronoamperometry, the Cottrell model has been generalized by taking into account a thin porosity layer covering the surface of the electrode and Tafel kinetics of an electrode reaction. The effective diffusion coefficient inside a porosity layer is calculated by Bruggeman’s law. It is shown that in the quasi-stationary approximation of diffusion inside a thin porous layer, the chronoamperometry problem can be solved analytically. The obtained solution has been compared with the results of direct numerical simulations and a good agreement is shown. Limiting cases of the solution related to low and high porosity are considered." @default.
- W4200518085 created "2021-12-31" @default.
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- W4200518085 date "2021-12-17" @default.
- W4200518085 modified "2023-10-06" @default.
- W4200518085 title "Influence of Diffusion through a Porous Film under Electrode Surface in Chronoamperometry Problems" @default.
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- W4200518085 doi "https://doi.org/10.4028/www.scientific.net/ddf.413.84" @default.
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