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• W4200520904 abstract "To develop a heterogeneous Fenton-like catalyst with desirable activity and reusability remains a great challenge for the practical degradation of environmental remediation. Herein, we demonstrate a dendritic Fe-Cu bimetallic catalyst consisted of a Cu/Fe3O4 shell and a FeCu core (E100). In comparisons of single Cu, Fe and Fe3O4, E100 performs far better performance for the Fenton-like degradation of phenol, and its dominant Fenton-like active centers are Fe species under acidic pH or Cu species under neutral pH. Particularly, Cu-based Fenton-like reactions are greatly accelerated by galvanic micro-cells effects that come from the special co-existence of Cu/Fe3O4 shell, and subsequently, owing to the Cu leaching from the shell, the inner FeCu core of E100 is able to be exposed and further strengthen Fe-based Fenton-like reactions. Overall, the appropriate synergistic effects endow E100 with superior catalytic activity and reusability than other catalysts. Our work pushes forward a step for understanding the catalytic mechanism of Fe-Cu bimetallic catalysts and provides new sights for fabricating efficient Fenton-like catalysts for environmental remediation." @default.
• W4200520904 created "2021-12-31" @default.
• W4200520904 creator A5080461157 @default.
• W4200520904 creator A5082866466 @default.
• W4200520904 creator A5085145733 @default.
• W4200520904 date "2022-02-01" @default.
• W4200520904 modified "2023-10-14" @default.
• W4200520904 title "Revealing the enhancing mechanisms of Fe–Cu bimetallic catalysts for the Fenton-like degradation of phenol" @default.
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• W4200520904 doi "https://doi.org/10.1016/j.chemosphere.2021.133195" @default.
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